[3-(Dimethyl­amino)benzoato]triphenyl­tin(IV)

In the title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NO(2))], the Sn atom is coordinated by three phenyl groups and a carboxyl­ate anion in a distorted tetra­hedral geometry. An intra­molecular C—H⋯O inter­action forms an S(7) ring motif. The dihedral angles between the benzoate group and the other thre...

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Autores principales: Win, Yip Foo, Teoh, Siang Guan, Ha, Sie Tiong, Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959792/
https://www.ncbi.nlm.nih.gov/pubmed/21581146
http://dx.doi.org/10.1107/S1600536808036337
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author Win, Yip Foo
Teoh, Siang Guan
Ha, Sie Tiong
Kia, Reza
Fun, Hoong-Kun
author_facet Win, Yip Foo
Teoh, Siang Guan
Ha, Sie Tiong
Kia, Reza
Fun, Hoong-Kun
author_sort Win, Yip Foo
collection PubMed
description In the title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NO(2))], the Sn atom is coordinated by three phenyl groups and a carboxyl­ate anion in a distorted tetra­hedral geometry. An intra­molecular C—H⋯O inter­action forms an S(7) ring motif. The dihedral angles between the benzoate group and the other three phenyl rings are 76.94 (8), 66.82 (8) and 42.34 (9)°. The crystal structure is further stabilized by inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29597922010-12-30 [3-(Dimethyl­amino)benzoato]triphenyl­tin(IV) Win, Yip Foo Teoh, Siang Guan Ha, Sie Tiong Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NO(2))], the Sn atom is coordinated by three phenyl groups and a carboxyl­ate anion in a distorted tetra­hedral geometry. An intra­molecular C—H⋯O inter­action forms an S(7) ring motif. The dihedral angles between the benzoate group and the other three phenyl rings are 76.94 (8), 66.82 (8) and 42.34 (9)°. The crystal structure is further stabilized by inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959792/ /pubmed/21581146 http://dx.doi.org/10.1107/S1600536808036337 Text en © Win et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Win, Yip Foo
Teoh, Siang Guan
Ha, Sie Tiong
Kia, Reza
Fun, Hoong-Kun
[3-(Dimethyl­amino)benzoato]triphenyl­tin(IV)
title [3-(Dimethyl­amino)benzoato]triphenyl­tin(IV)
title_full [3-(Dimethyl­amino)benzoato]triphenyl­tin(IV)
title_fullStr [3-(Dimethyl­amino)benzoato]triphenyl­tin(IV)
title_full_unstemmed [3-(Dimethyl­amino)benzoato]triphenyl­tin(IV)
title_short [3-(Dimethyl­amino)benzoato]triphenyl­tin(IV)
title_sort [3-(dimethyl­amino)benzoato]triphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959792/
https://www.ncbi.nlm.nih.gov/pubmed/21581146
http://dx.doi.org/10.1107/S1600536808036337
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AT hasietiong 3dimethylaminobenzoatotriphenyltiniv
AT kiareza 3dimethylaminobenzoatotriphenyltiniv
AT funhoongkun 3dimethylaminobenzoatotriphenyltiniv

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