Bis[benzyl N′-(1H-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) N′,S]nickel(II) N,N-dimethyl­formamide disolvate

In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Ni atom (site symmetry [Image: see text]) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the cry...

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Detalles Bibliográficos
Autores principales: Khaledi, Hamid, Mohd Ali, Hapipah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959798/
https://www.ncbi.nlm.nih.gov/pubmed/21581208
http://dx.doi.org/10.1107/S1600536808038580
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author Khaledi, Hamid
Mohd Ali, Hapipah
Ng, Seik Weng
author_facet Khaledi, Hamid
Mohd Ali, Hapipah
Ng, Seik Weng
author_sort Khaledi, Hamid
collection PubMed
description In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Ni atom (site symmetry [Image: see text]) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N—H⋯O hydrogen bond links the complex to the dimethyl­formamide solvent mol­ecule.
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spelling pubmed-29597982010-12-30 Bis[benzyl N′-(1H-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) N′,S]nickel(II) N,N-dimethyl­formamide disolvate Khaledi, Hamid Mohd Ali, Hapipah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Ni atom (site symmetry [Image: see text]) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N—H⋯O hydrogen bond links the complex to the dimethyl­formamide solvent mol­ecule. International Union of Crystallography 2008-11-26 /pmc/articles/PMC2959798/ /pubmed/21581208 http://dx.doi.org/10.1107/S1600536808038580 Text en © Khaledi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khaledi, Hamid
Mohd Ali, Hapipah
Ng, Seik Weng
Bis[benzyl N′-(1H-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) N′,S]nickel(II) N,N-dimethyl­formamide disolvate
title Bis[benzyl N′-(1H-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) N′,S]nickel(II) N,N-dimethyl­formamide disolvate
title_full Bis[benzyl N′-(1H-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) N′,S]nickel(II) N,N-dimethyl­formamide disolvate
title_fullStr Bis[benzyl N′-(1H-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) N′,S]nickel(II) N,N-dimethyl­formamide disolvate
title_full_unstemmed Bis[benzyl N′-(1H-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) N′,S]nickel(II) N,N-dimethyl­formamide disolvate
title_short Bis[benzyl N′-(1H-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) N′,S]nickel(II) N,N-dimethyl­formamide disolvate
title_sort bis[benzyl n′-(1h-indol-3-ylmethyl­ene)hydrazinecarbodithio­ato-κ(2) n′,s]nickel(ii) n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959798/
https://www.ncbi.nlm.nih.gov/pubmed/21581208
http://dx.doi.org/10.1107/S1600536808038580
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AT mohdalihapipah bisbenzyln1hindol3ylmethylenehydrazinecarbodithioatok2nsnickeliinndimethylformamidedisolvate
AT ngseikweng bisbenzyln1hindol3ylmethylenehydrazinecarbodithioatok2nsnickeliinndimethylformamidedisolvate

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