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Bis(4-ferrocenylbenzoato-κO)tetra­kis(methanol-κO)cadmium(II)

The complete mol­ecule of the title compound, [CdFe(2)(C(5)H(5))(2)(C(12)H(8)O(2))(2)(CH(4)O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol mol­ecules and by the O atoms of the two c...

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Detalles Bibliográficos
Autores principales: Zhao, Hong-Ying, Song, Lian-Qing, Wang, Jing-Wu, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959802/
https://www.ncbi.nlm.nih.gov/pubmed/21581214
http://dx.doi.org/10.1107/S160053680803907X
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author Zhao, Hong-Ying
Song, Lian-Qing
Wang, Jing-Wu
Ng, Seik Weng
author_facet Zhao, Hong-Ying
Song, Lian-Qing
Wang, Jing-Wu
Ng, Seik Weng
author_sort Zhao, Hong-Ying
collection PubMed
description The complete mol­ecule of the title compound, [CdFe(2)(C(5)H(5))(2)(C(12)H(8)O(2))(2)(CH(4)O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol mol­ecules and by the O atoms of the two carboxyl­ate anions (the latter in cis geometry), resulting in a distorted CdO(6) octa­hedron. The phenyl­ene ring is almost coplanar with its adjacent cyclo­penta­dienyl ring [dihedral angle = 8.2 (2)°]. The uncoordin­ated carboxyl­ate O atom acts as acceptor to two O—H⋯O hydrogen bonds from the methanol mol­ecules, giving rise to a layered network.
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spelling pubmed-29598022010-12-30 Bis(4-ferrocenylbenzoato-κO)tetra­kis(methanol-κO)cadmium(II) Zhao, Hong-Ying Song, Lian-Qing Wang, Jing-Wu Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title compound, [CdFe(2)(C(5)H(5))(2)(C(12)H(8)O(2))(2)(CH(4)O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol mol­ecules and by the O atoms of the two carboxyl­ate anions (the latter in cis geometry), resulting in a distorted CdO(6) octa­hedron. The phenyl­ene ring is almost coplanar with its adjacent cyclo­penta­dienyl ring [dihedral angle = 8.2 (2)°]. The uncoordin­ated carboxyl­ate O atom acts as acceptor to two O—H⋯O hydrogen bonds from the methanol mol­ecules, giving rise to a layered network. International Union of Crystallography 2008-11-26 /pmc/articles/PMC2959802/ /pubmed/21581214 http://dx.doi.org/10.1107/S160053680803907X Text en © Zhao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Hong-Ying
Song, Lian-Qing
Wang, Jing-Wu
Ng, Seik Weng
Bis(4-ferrocenylbenzoato-κO)tetra­kis(methanol-κO)cadmium(II)
title Bis(4-ferrocenylbenzoato-κO)tetra­kis(methanol-κO)cadmium(II)
title_full Bis(4-ferrocenylbenzoato-κO)tetra­kis(methanol-κO)cadmium(II)
title_fullStr Bis(4-ferrocenylbenzoato-κO)tetra­kis(methanol-κO)cadmium(II)
title_full_unstemmed Bis(4-ferrocenylbenzoato-κO)tetra­kis(methanol-κO)cadmium(II)
title_short Bis(4-ferrocenylbenzoato-κO)tetra­kis(methanol-κO)cadmium(II)
title_sort bis(4-ferrocenylbenzoato-κo)tetra­kis(methanol-κo)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959802/
https://www.ncbi.nlm.nih.gov/pubmed/21581214
http://dx.doi.org/10.1107/S160053680803907X
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