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Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II)
The complete molecule of the title compound, [CdFe(2)(C(5)H(5))(2)(C(12)H(8)O(2))(2)(CH(4)O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol molecules and by the O atoms of the two c...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959802/ https://www.ncbi.nlm.nih.gov/pubmed/21581214 http://dx.doi.org/10.1107/S160053680803907X |
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author | Zhao, Hong-Ying Song, Lian-Qing Wang, Jing-Wu Ng, Seik Weng |
author_facet | Zhao, Hong-Ying Song, Lian-Qing Wang, Jing-Wu Ng, Seik Weng |
author_sort | Zhao, Hong-Ying |
collection | PubMed |
description | The complete molecule of the title compound, [CdFe(2)(C(5)H(5))(2)(C(12)H(8)O(2))(2)(CH(4)O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol molecules and by the O atoms of the two carboxylate anions (the latter in cis geometry), resulting in a distorted CdO(6) octahedron. The phenylene ring is almost coplanar with its adjacent cyclopentadienyl ring [dihedral angle = 8.2 (2)°]. The uncoordinated carboxylate O atom acts as acceptor to two O—H⋯O hydrogen bonds from the methanol molecules, giving rise to a layered network. |
format | Text |
id | pubmed-2959802 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598022010-12-30 Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II) Zhao, Hong-Ying Song, Lian-Qing Wang, Jing-Wu Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the title compound, [CdFe(2)(C(5)H(5))(2)(C(12)H(8)O(2))(2)(CH(4)O)(4)], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol molecules and by the O atoms of the two carboxylate anions (the latter in cis geometry), resulting in a distorted CdO(6) octahedron. The phenylene ring is almost coplanar with its adjacent cyclopentadienyl ring [dihedral angle = 8.2 (2)°]. The uncoordinated carboxylate O atom acts as acceptor to two O—H⋯O hydrogen bonds from the methanol molecules, giving rise to a layered network. International Union of Crystallography 2008-11-26 /pmc/articles/PMC2959802/ /pubmed/21581214 http://dx.doi.org/10.1107/S160053680803907X Text en © Zhao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Hong-Ying Song, Lian-Qing Wang, Jing-Wu Ng, Seik Weng Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II) |
title | Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II) |
title_full | Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II) |
title_fullStr | Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II) |
title_full_unstemmed | Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II) |
title_short | Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II) |
title_sort | bis(4-ferrocenylbenzoato-κo)tetrakis(methanol-κo)cadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959802/ https://www.ncbi.nlm.nih.gov/pubmed/21581214 http://dx.doi.org/10.1107/S160053680803907X |
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