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catena-Poly[[aqua(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitroisophthalato-κ(3) O (1),O (1′):O (3)]
In the asymmetric unit of the title compound, [Cu(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers related by a non-crystallographic inversion center. Within the polymers, the Cu(II )atoms, coordinated by the water molecule and the c...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959803/ https://www.ncbi.nlm.nih.gov/pubmed/21581121 http://dx.doi.org/10.1107/S1600536808035150 |
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author | Hao, Lujiang Liu, Xia |
author_facet | Hao, Lujiang Liu, Xia |
author_sort | Hao, Lujiang |
collection | PubMed |
description | In the asymmetric unit of the title compound, [Cu(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers related by a non-crystallographic inversion center. Within the polymers, the Cu(II )atoms, coordinated by the water molecule and the chelating 2,2′-bipyridine ligands, are bridged by 5-nitrobenzene-1,3-dicarboxylate dianions which act as tridentate ligands; the carboxylate groups exhibit monodentate and symmetric bidentate coordination modes. The Cu(II) atoms show a strongly distorted octahedral coordination geometry. In the crystal structure, the two symmetry-independent coordination polymers form another one-dimensional polymeric structure via O—H⋯O hydrogen bonds between coordinated water molecules and carboxylate groups. |
format | Text |
id | pubmed-2959803 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598032010-12-30 catena-Poly[[aqua(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitroisophthalato-κ(3) O (1),O (1′):O (3)] Hao, Lujiang Liu, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title compound, [Cu(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers related by a non-crystallographic inversion center. Within the polymers, the Cu(II )atoms, coordinated by the water molecule and the chelating 2,2′-bipyridine ligands, are bridged by 5-nitrobenzene-1,3-dicarboxylate dianions which act as tridentate ligands; the carboxylate groups exhibit monodentate and symmetric bidentate coordination modes. The Cu(II) atoms show a strongly distorted octahedral coordination geometry. In the crystal structure, the two symmetry-independent coordination polymers form another one-dimensional polymeric structure via O—H⋯O hydrogen bonds between coordinated water molecules and carboxylate groups. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959803/ /pubmed/21581121 http://dx.doi.org/10.1107/S1600536808035150 Text en © Hao and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hao, Lujiang Liu, Xia catena-Poly[[aqua(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitroisophthalato-κ(3) O (1),O (1′):O (3)] |
title |
catena-Poly[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-5-nitroisophthalato-κ(3)
O
(1),O
(1′):O
(3)] |
title_full |
catena-Poly[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-5-nitroisophthalato-κ(3)
O
(1),O
(1′):O
(3)] |
title_fullStr |
catena-Poly[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-5-nitroisophthalato-κ(3)
O
(1),O
(1′):O
(3)] |
title_full_unstemmed |
catena-Poly[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-5-nitroisophthalato-κ(3)
O
(1),O
(1′):O
(3)] |
title_short |
catena-Poly[[aqua(2,2′-bipyridine-κ(2)
N,N′)copper(II)]-μ-5-nitroisophthalato-κ(3)
O
(1),O
(1′):O
(3)] |
title_sort | catena-poly[[aqua(2,2′-bipyridine-κ(2)
n,n′)copper(ii)]-μ-5-nitroisophthalato-κ(3)
o
(1),o
(1′):o
(3)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959803/ https://www.ncbi.nlm.nih.gov/pubmed/21581121 http://dx.doi.org/10.1107/S1600536808035150 |
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