Cargando…

catena-Poly[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitro­isophthalato-κ(3) O (1),O (1′):O (3)]

In the asymmetric unit of the title compound, [Cu(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers related by a non-crystallographic inversion center. Within the polymers, the Cu(II )atoms, coordinated by the water mol­ecule and the c...

Descripción completa

Detalles Bibliográficos
Autores principales: Hao, Lujiang, Liu, Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959803/
https://www.ncbi.nlm.nih.gov/pubmed/21581121
http://dx.doi.org/10.1107/S1600536808035150
_version_ 1782188587126620160
author Hao, Lujiang
Liu, Xia
author_facet Hao, Lujiang
Liu, Xia
author_sort Hao, Lujiang
collection PubMed
description In the asymmetric unit of the title compound, [Cu(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers related by a non-crystallographic inversion center. Within the polymers, the Cu(II )atoms, coordinated by the water mol­ecule and the chelating 2,2′-bipyridine ligands, are bridged by 5-nitro­benzene-1,3-dicarboxyl­ate dianions which act as tridentate ligands; the carboxyl­ate groups exhibit monodentate and symmetric bidentate coordination modes. The Cu(II) atoms show a strongly distorted octa­hedral coordination geometry. In the crystal structure, the two symmetry-independent coordination polymers form another one-dimensional polymeric structure via O—H⋯O hydrogen bonds between coordinated water mol­ecules and carboxyl­ate groups.
format Text
id pubmed-2959803
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29598032010-12-30 catena-Poly[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitro­isophthalato-κ(3) O (1),O (1′):O (3)] Hao, Lujiang Liu, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of the title compound, [Cu(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers related by a non-crystallographic inversion center. Within the polymers, the Cu(II )atoms, coordinated by the water mol­ecule and the chelating 2,2′-bipyridine ligands, are bridged by 5-nitro­benzene-1,3-dicarboxyl­ate dianions which act as tridentate ligands; the carboxyl­ate groups exhibit monodentate and symmetric bidentate coordination modes. The Cu(II) atoms show a strongly distorted octa­hedral coordination geometry. In the crystal structure, the two symmetry-independent coordination polymers form another one-dimensional polymeric structure via O—H⋯O hydrogen bonds between coordinated water mol­ecules and carboxyl­ate groups. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959803/ /pubmed/21581121 http://dx.doi.org/10.1107/S1600536808035150 Text en © Hao and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Lujiang
Liu, Xia
catena-Poly[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitro­isophthalato-κ(3) O (1),O (1′):O (3)]
title catena-Poly[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitro­isophthalato-κ(3) O (1),O (1′):O (3)]
title_full catena-Poly[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitro­isophthalato-κ(3) O (1),O (1′):O (3)]
title_fullStr catena-Poly[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitro­isophthalato-κ(3) O (1),O (1′):O (3)]
title_full_unstemmed catena-Poly[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitro­isophthalato-κ(3) O (1),O (1′):O (3)]
title_short catena-Poly[[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)]-μ-5-nitro­isophthalato-κ(3) O (1),O (1′):O (3)]
title_sort catena-poly[[aqua­(2,2′-bipyridine-κ(2) n,n′)copper(ii)]-μ-5-nitro­isophthalato-κ(3) o (1),o (1′):o (3)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959803/
https://www.ncbi.nlm.nih.gov/pubmed/21581121
http://dx.doi.org/10.1107/S1600536808035150
work_keys_str_mv AT haolujiang catenapolyaqua22bipyridinek2nncopperiim5nitroisophthalatok3o1o1o3
AT liuxia catenapolyaqua22bipyridinek2nncopperiim5nitroisophthalatok3o1o1o3