Ag(2)PdP(2)O(7)

Disilver(I) palladium(II) diphosphate, Ag(2)PdP(2)O(7), is isotypic with Na(2)PdP(2)O(7). It consists of infinite diphosphato-pallad­ate(II) [Pd(P(2)O(7))(2/2)](2−) ribbons with the Pd(II) ion in an almost square-planar coordination ([Image: see text] symmetry) and the P(2)O(7) group exhibiting 2 sy...

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Detalles Bibliográficos
Autores principales: Panagiotidis, Kosta, Glaum, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959806/
https://www.ncbi.nlm.nih.gov/pubmed/21581108
http://dx.doi.org/10.1107/S1600536808038518
Descripción
Sumario:Disilver(I) palladium(II) diphosphate, Ag(2)PdP(2)O(7), is isotypic with Na(2)PdP(2)O(7). It consists of infinite diphosphato-pallad­ate(II) [Pd(P(2)O(7))(2/2)](2−) ribbons with the Pd(II) ion in an almost square-planar coordination ([Image: see text] symmetry) and the P(2)O(7) group exhibiting 2 symmetry. The [Pd(P(2)O(7))(2/2)](2−) ribbons are linked by distorted [AgO(6)] octa­hedra. (31)P-MAS NMR studies on Ag(2)PdP(2)O(7) are in accordance with one independent site for phospho­rus; its isotropic chemical shift δ(iso) = 21.5 p.p.m. is similar to that of Pd(2)P(2)O(7).

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