Ag(2)PdP(2)O(7)

Disilver(I) palladium(II) diphosphate, Ag(2)PdP(2)O(7), is isotypic with Na(2)PdP(2)O(7). It consists of infinite diphosphato-pallad­ate(II) [Pd(P(2)O(7))(2/2)](2−) ribbons with the Pd(II) ion in an almost square-planar coordination ([Image: see text] symmetry) and the P(2)O(7) group exhibiting 2 sy...

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Detalles Bibliográficos
Autores principales: Panagiotidis, Kosta, Glaum, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959806/
https://www.ncbi.nlm.nih.gov/pubmed/21581108
http://dx.doi.org/10.1107/S1600536808038518
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author Panagiotidis, Kosta
Glaum, Robert
author_facet Panagiotidis, Kosta
Glaum, Robert
author_sort Panagiotidis, Kosta
collection PubMed
description Disilver(I) palladium(II) diphosphate, Ag(2)PdP(2)O(7), is isotypic with Na(2)PdP(2)O(7). It consists of infinite diphosphato-pallad­ate(II) [Pd(P(2)O(7))(2/2)](2−) ribbons with the Pd(II) ion in an almost square-planar coordination ([Image: see text] symmetry) and the P(2)O(7) group exhibiting 2 symmetry. The [Pd(P(2)O(7))(2/2)](2−) ribbons are linked by distorted [AgO(6)] octa­hedra. (31)P-MAS NMR studies on Ag(2)PdP(2)O(7) are in accordance with one independent site for phospho­rus; its isotropic chemical shift δ(iso) = 21.5 p.p.m. is similar to that of Pd(2)P(2)O(7).
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spelling pubmed-29598062010-12-30 Ag(2)PdP(2)O(7) Panagiotidis, Kosta Glaum, Robert Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Disilver(I) palladium(II) diphosphate, Ag(2)PdP(2)O(7), is isotypic with Na(2)PdP(2)O(7). It consists of infinite diphosphato-pallad­ate(II) [Pd(P(2)O(7))(2/2)](2−) ribbons with the Pd(II) ion in an almost square-planar coordination ([Image: see text] symmetry) and the P(2)O(7) group exhibiting 2 symmetry. The [Pd(P(2)O(7))(2/2)](2−) ribbons are linked by distorted [AgO(6)] octa­hedra. (31)P-MAS NMR studies on Ag(2)PdP(2)O(7) are in accordance with one independent site for phospho­rus; its isotropic chemical shift δ(iso) = 21.5 p.p.m. is similar to that of Pd(2)P(2)O(7). International Union of Crystallography 2008-11-29 /pmc/articles/PMC2959806/ /pubmed/21581108 http://dx.doi.org/10.1107/S1600536808038518 Text en © Panagiotidis and Glaum 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Panagiotidis, Kosta
Glaum, Robert
Ag(2)PdP(2)O(7)
title Ag(2)PdP(2)O(7)
title_full Ag(2)PdP(2)O(7)
title_fullStr Ag(2)PdP(2)O(7)
title_full_unstemmed Ag(2)PdP(2)O(7)
title_short Ag(2)PdP(2)O(7)
title_sort ag(2)pdp(2)o(7)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959806/
https://www.ncbi.nlm.nih.gov/pubmed/21581108
http://dx.doi.org/10.1107/S1600536808038518
work_keys_str_mv AT panagiotidiskosta ag2pdp2o7
AT glaumrobert ag2pdp2o7

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