4-[(4-Amino-3-pyrid­yl)imino­meth­yl]benzonitrile

The asymmetric unit of the potential mono-Schiff base ligand title compound, C(13)H(10)N(4), contains two crystallographically independent mol­ecules, A and B. In mol­ecule A, the two rings are twisted from each other by 13.90 (18)°. By contrast, the dihedral angle between the two rings in mol­ecule...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kargar, Hadi, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959807/
https://www.ncbi.nlm.nih.gov/pubmed/21581317
http://dx.doi.org/10.1107/S1600536808037070
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author Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
author_facet Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the potential mono-Schiff base ligand title compound, C(13)H(10)N(4), contains two crystallographically independent mol­ecules, A and B. In mol­ecule A, the two rings are twisted from each other by 13.90 (18)°. By contrast, the dihedral angle between the two rings in mol­ecule B is 0.67 (19)°. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯N inter­actions via R(4)(4)(32) motifs, forming two-dimensional arrays. The short distances between the centroids of the six-membered rings indicate the existence of π–π inter­actions [centroid–centroid distances = 3.6880 (17)–3.7466 (15) Å].
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spelling pubmed-29598072010-12-30 4-[(4-Amino-3-pyrid­yl)imino­meth­yl]benzonitrile Fun, Hoong-Kun Kargar, Hadi Kia, Reza Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the potential mono-Schiff base ligand title compound, C(13)H(10)N(4), contains two crystallographically independent mol­ecules, A and B. In mol­ecule A, the two rings are twisted from each other by 13.90 (18)°. By contrast, the dihedral angle between the two rings in mol­ecule B is 0.67 (19)°. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯N inter­actions via R(4)(4)(32) motifs, forming two-dimensional arrays. The short distances between the centroids of the six-membered rings indicate the existence of π–π inter­actions [centroid–centroid distances = 3.6880 (17)–3.7466 (15) Å]. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959807/ /pubmed/21581317 http://dx.doi.org/10.1107/S1600536808037070 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
4-[(4-Amino-3-pyrid­yl)imino­meth­yl]benzonitrile
title 4-[(4-Amino-3-pyrid­yl)imino­meth­yl]benzonitrile
title_full 4-[(4-Amino-3-pyrid­yl)imino­meth­yl]benzonitrile
title_fullStr 4-[(4-Amino-3-pyrid­yl)imino­meth­yl]benzonitrile
title_full_unstemmed 4-[(4-Amino-3-pyrid­yl)imino­meth­yl]benzonitrile
title_short 4-[(4-Amino-3-pyrid­yl)imino­meth­yl]benzonitrile
title_sort 4-[(4-amino-3-pyrid­yl)imino­meth­yl]benzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959807/
https://www.ncbi.nlm.nih.gov/pubmed/21581317
http://dx.doi.org/10.1107/S1600536808037070
work_keys_str_mv AT funhoongkun 44amino3pyridyliminomethylbenzonitrile
AT kargarhadi 44amino3pyridyliminomethylbenzonitrile
AT kiareza 44amino3pyridyliminomethylbenzonitrile

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