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5,5′-Dimethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
The asymmetric unit of the title Schiff base compound, C(21)H(26)N(2)O(4), consists of four crystallographically independent molecules, viz. A, B, C and D. The A and D, and the B and C molecules are related by a pseudo-inversion centre, and the remaining pairs of molecules differ in the orientati...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959808/ https://www.ncbi.nlm.nih.gov/pubmed/21581360 http://dx.doi.org/10.1107/S1600536808037690 |
Sumario: | The asymmetric unit of the title Schiff base compound, C(21)H(26)N(2)O(4), consists of four crystallographically independent molecules, viz. A, B, C and D. The A and D, and the B and C molecules are related by a pseudo-inversion centre, and the remaining pairs of molecules differ in the orientations of one of the methoxy groups. In each independent molecule, intramolecular O—H⋯N hydrogen bonds generate two S(6) ring motifs. The dihedral angles between the benzene rings in molecules A, B, C and D are 65.86 (19), 50.41 (19), 68.59 (19) and 50.85 (19)°, respectively. In the crystal structure, molecules are linked by C—H⋯O hydrogen bonds, forming R (2) (2)(8) dimers. In addition, weak C—H⋯π interactions are observed. |
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