Bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(II)]

The structure of the title compound, (C(24)H(20)P)(2)[Te(2)I(6)], is composed of discrete PPh(4) (+) cations and centrosymmetric [Te(2)I(6)](2−) anions. The tellurium(II) atom shows a sligthly distorted square-planar TeI(4) geometry and is coordinated to two bridging and two terminal iodine atoms. T...

Descripción completa

Detalles Bibliográficos
Autores principales: Närhi, Sari M., Oilunkaniemi, Raija, Laitinen, Risto S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959816/
https://www.ncbi.nlm.nih.gov/pubmed/21581168
http://dx.doi.org/10.1107/S1600536808035927
_version_ 1782188590259765248
author Närhi, Sari M.
Oilunkaniemi, Raija
Laitinen, Risto S.
author_facet Närhi, Sari M.
Oilunkaniemi, Raija
Laitinen, Risto S.
author_sort Närhi, Sari M.
collection PubMed
description The structure of the title compound, (C(24)H(20)P)(2)[Te(2)I(6)], is composed of discrete PPh(4) (+) cations and centrosymmetric [Te(2)I(6)](2−) anions. The tellurium(II) atom shows a sligthly distorted square-planar TeI(4) geometry and is coordinated to two bridging and two terminal iodine atoms. The planar [Te(2)I(6)](2−) ions are isolated by the cations and no inter­molecular tellurium–halogen or halogen–halogen inter­actions are present.
format Text
id pubmed-2959816
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29598162010-12-30 Bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(II)] Närhi, Sari M. Oilunkaniemi, Raija Laitinen, Risto S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(24)H(20)P)(2)[Te(2)I(6)], is composed of discrete PPh(4) (+) cations and centrosymmetric [Te(2)I(6)](2−) anions. The tellurium(II) atom shows a sligthly distorted square-planar TeI(4) geometry and is coordinated to two bridging and two terminal iodine atoms. The planar [Te(2)I(6)](2−) ions are isolated by the cations and no inter­molecular tellurium–halogen or halogen–halogen inter­actions are present. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959816/ /pubmed/21581168 http://dx.doi.org/10.1107/S1600536808035927 Text en © Närhi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Närhi, Sari M.
Oilunkaniemi, Raija
Laitinen, Risto S.
Bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(II)]
title Bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(II)]
title_full Bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(II)]
title_fullStr Bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(II)]
title_full_unstemmed Bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(II)]
title_short Bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(II)]
title_sort bis(tetra­phenyl­phospho­nium) di-μ-iodido-bis[di­iodido­tellurate(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959816/
https://www.ncbi.nlm.nih.gov/pubmed/21581168
http://dx.doi.org/10.1107/S1600536808035927
work_keys_str_mv AT narhisarim bistetraphenylphosphoniumdimiodidobisdiiodidotellurateii
AT oilunkaniemiraija bistetraphenylphosphoniumdimiodidobisdiiodidotellurateii
AT laitinenristos bistetraphenylphosphoniumdimiodidobisdiiodidotellurateii

Ejemplares similares