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{N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II)

In the title compound, [ZnCl(2)(C(20)H(20)N(2))], the Zn(II) atom is four coordinated in a distorted tetra­hedral geometry by two N atoms of the Schiff base ligand and by two Cl atoms. Edge-to-face C—H⋯π inter­actions exist between mol­ecules, with a dihedral angle of 37.8 (1)° between the benzene r...

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Detalles Bibliográficos
Autores principales: Cai, Hong-Lan, Liu, Bing, Lin, Zhi-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959818/
https://www.ncbi.nlm.nih.gov/pubmed/21581194
http://dx.doi.org/10.1107/S1600536808037860
Descripción
Sumario:In the title compound, [ZnCl(2)(C(20)H(20)N(2))], the Zn(II) atom is four coordinated in a distorted tetra­hedral geometry by two N atoms of the Schiff base ligand and by two Cl atoms. Edge-to-face C—H⋯π inter­actions exist between mol­ecules, with a dihedral angle of 37.8 (1)° between the benzene ring planes and a shortest H⋯centroid distance of 3.62 (5) Å.