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{N,N′-Bis[(E)-3-phenylallylidene]ethane-1,2-diamine}dichloridozinc(II)
In the title compound, [ZnCl(2)(C(20)H(20)N(2))], the Zn(II) atom is four coordinated in a distorted tetrahedral geometry by two N atoms of the Schiff base ligand and by two Cl atoms. Edge-to-face C—H⋯π interactions exist between molecules, with a dihedral angle of 37.8 (1)° between the benzene r...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959818/ https://www.ncbi.nlm.nih.gov/pubmed/21581194 http://dx.doi.org/10.1107/S1600536808037860 |
Sumario: | In the title compound, [ZnCl(2)(C(20)H(20)N(2))], the Zn(II) atom is four coordinated in a distorted tetrahedral geometry by two N atoms of the Schiff base ligand and by two Cl atoms. Edge-to-face C—H⋯π interactions exist between molecules, with a dihedral angle of 37.8 (1)° between the benzene ring planes and a shortest H⋯centroid distance of 3.62 (5) Å. |
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