{N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II)

In the title compound, [ZnCl(2)(C(20)H(20)N(2))], the Zn(II) atom is four coordinated in a distorted tetra­hedral geometry by two N atoms of the Schiff base ligand and by two Cl atoms. Edge-to-face C—H⋯π inter­actions exist between mol­ecules, with a dihedral angle of 37.8 (1)° between the benzene r...

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Detalles Bibliográficos
Autores principales: Cai, Hong-Lan, Liu, Bing, Lin, Zhi-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959818/
https://www.ncbi.nlm.nih.gov/pubmed/21581194
http://dx.doi.org/10.1107/S1600536808037860
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author Cai, Hong-Lan
Liu, Bing
Lin, Zhi-Dong
author_facet Cai, Hong-Lan
Liu, Bing
Lin, Zhi-Dong
author_sort Cai, Hong-Lan
collection PubMed
description In the title compound, [ZnCl(2)(C(20)H(20)N(2))], the Zn(II) atom is four coordinated in a distorted tetra­hedral geometry by two N atoms of the Schiff base ligand and by two Cl atoms. Edge-to-face C—H⋯π inter­actions exist between mol­ecules, with a dihedral angle of 37.8 (1)° between the benzene ring planes and a shortest H⋯centroid distance of 3.62 (5) Å.
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spelling pubmed-29598182010-12-30 {N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II) Cai, Hong-Lan Liu, Bing Lin, Zhi-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(20)H(20)N(2))], the Zn(II) atom is four coordinated in a distorted tetra­hedral geometry by two N atoms of the Schiff base ligand and by two Cl atoms. Edge-to-face C—H⋯π inter­actions exist between mol­ecules, with a dihedral angle of 37.8 (1)° between the benzene ring planes and a shortest H⋯centroid distance of 3.62 (5) Å. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959818/ /pubmed/21581194 http://dx.doi.org/10.1107/S1600536808037860 Text en © Cai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Hong-Lan
Liu, Bing
Lin, Zhi-Dong
{N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II)
title {N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II)
title_full {N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II)
title_fullStr {N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II)
title_full_unstemmed {N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II)
title_short {N,N′-Bis[(E)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(II)
title_sort {n,n′-bis[(e)-3-phenyl­allyl­idene]ethane-1,2-diamine}dichloridozinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959818/
https://www.ncbi.nlm.nih.gov/pubmed/21581194
http://dx.doi.org/10.1107/S1600536808037860
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