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Diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxybenzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate
In the title compound, [Co(C(7)H(5)O(3))(C(14)H(12)N(2))(H(2)O)(2)]NO(3)·2H(2)O, the Co(II) ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxylate O atoms of one 4-hydroxybenzoate anion and two O atoms of two water molecules, in a distorted oc...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959819/ https://www.ncbi.nlm.nih.gov/pubmed/21581191 http://dx.doi.org/10.1107/S1600536808038117 |
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author | Zhai, Cuiping Yan, Fengmei Zhao, Peizheng |
author_facet | Zhai, Cuiping Yan, Fengmei Zhao, Peizheng |
author_sort | Zhai, Cuiping |
collection | PubMed |
description | In the title compound, [Co(C(7)H(5)O(3))(C(14)H(12)N(2))(H(2)O)(2)]NO(3)·2H(2)O, the Co(II) ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxylate O atoms of one 4-hydroxybenzoate anion and two O atoms of two water molecules, in a distorted octahedral environment; the two water molecules occupy the apical positions. In the crystal structure, the ionic units and water molecules are linked through O—H⋯O hydrogen bonds, leading to the formation of a three-dimensional network. In addition, π–π interactions between a pyridine ring of the dmphen ligand and the benzene ring of the hydroxybenzoate anion [centroid–centroid separation = 3.6861 (3) Å] are observed. |
format | Text |
id | pubmed-2959819 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598192010-12-30 Diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxybenzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate Zhai, Cuiping Yan, Fengmei Zhao, Peizheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(5)O(3))(C(14)H(12)N(2))(H(2)O)(2)]NO(3)·2H(2)O, the Co(II) ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxylate O atoms of one 4-hydroxybenzoate anion and two O atoms of two water molecules, in a distorted octahedral environment; the two water molecules occupy the apical positions. In the crystal structure, the ionic units and water molecules are linked through O—H⋯O hydrogen bonds, leading to the formation of a three-dimensional network. In addition, π–π interactions between a pyridine ring of the dmphen ligand and the benzene ring of the hydroxybenzoate anion [centroid–centroid separation = 3.6861 (3) Å] are observed. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959819/ /pubmed/21581191 http://dx.doi.org/10.1107/S1600536808038117 Text en © Zhai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhai, Cuiping Yan, Fengmei Zhao, Peizheng Diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxybenzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate |
title | Diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)cobalt(II) nitrate dihydrate |
title_full | Diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)cobalt(II) nitrate dihydrate |
title_fullStr | Diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)cobalt(II) nitrate dihydrate |
title_full_unstemmed | Diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)cobalt(II) nitrate dihydrate |
title_short | Diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(4-hydroxybenzoato-κ(2)
O,O′)cobalt(II) nitrate dihydrate |
title_sort | diaqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)(4-hydroxybenzoato-κ(2)
o,o′)cobalt(ii) nitrate dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959819/ https://www.ncbi.nlm.nih.gov/pubmed/21581191 http://dx.doi.org/10.1107/S1600536808038117 |
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