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Diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxy­benzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate

In the title compound, [Co(C(7)H(5)O(3))(C(14)H(12)N(2))(H(2)O)(2)]NO(3)·2H(2)O, the Co(II) ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxyl­ate O atoms of one 4-hydroxy­benzoate anion and two O atoms of two water mol­ecules, in a distorted oc...

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Detalles Bibliográficos
Autores principales: Zhai, Cuiping, Yan, Fengmei, Zhao, Peizheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959819/
https://www.ncbi.nlm.nih.gov/pubmed/21581191
http://dx.doi.org/10.1107/S1600536808038117
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author Zhai, Cuiping
Yan, Fengmei
Zhao, Peizheng
author_facet Zhai, Cuiping
Yan, Fengmei
Zhao, Peizheng
author_sort Zhai, Cuiping
collection PubMed
description In the title compound, [Co(C(7)H(5)O(3))(C(14)H(12)N(2))(H(2)O)(2)]NO(3)·2H(2)O, the Co(II) ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxyl­ate O atoms of one 4-hydroxy­benzoate anion and two O atoms of two water mol­ecules, in a distorted octa­hedral environment; the two water mol­ecules occupy the apical positions. In the crystal structure, the ionic units and water mol­ecules are linked through O—H⋯O hydrogen bonds, leading to the formation of a three-dimensional network. In addition, π–π inter­actions between a pyridine ring of the dmphen ligand and the benzene ring of the hydroxy­benzoate anion [centroid–centroid separation = 3.6861 (3) Å] are observed.
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spelling pubmed-29598192010-12-30 Diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxy­benzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate Zhai, Cuiping Yan, Fengmei Zhao, Peizheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(5)O(3))(C(14)H(12)N(2))(H(2)O)(2)]NO(3)·2H(2)O, the Co(II) ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxyl­ate O atoms of one 4-hydroxy­benzoate anion and two O atoms of two water mol­ecules, in a distorted octa­hedral environment; the two water mol­ecules occupy the apical positions. In the crystal structure, the ionic units and water mol­ecules are linked through O—H⋯O hydrogen bonds, leading to the formation of a three-dimensional network. In addition, π–π inter­actions between a pyridine ring of the dmphen ligand and the benzene ring of the hydroxy­benzoate anion [centroid–centroid separation = 3.6861 (3) Å] are observed. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959819/ /pubmed/21581191 http://dx.doi.org/10.1107/S1600536808038117 Text en © Zhai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhai, Cuiping
Yan, Fengmei
Zhao, Peizheng
Diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxy­benzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate
title Diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxy­benzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate
title_full Diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxy­benzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate
title_fullStr Diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxy­benzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate
title_full_unstemmed Diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxy­benzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate
title_short Diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(4-hydroxy­benzoato-κ(2) O,O′)cobalt(II) nitrate dihydrate
title_sort diaqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)(4-hydroxy­benzoato-κ(2) o,o′)cobalt(ii) nitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959819/
https://www.ncbi.nlm.nih.gov/pubmed/21581191
http://dx.doi.org/10.1107/S1600536808038117
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