catena-Poly[[[(dimethyl­malonato-κ(2) O:O′)(perchlorato-κO)copper(II)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) N (1′):N (4′)] perchlorate dihydrate]

In the title compound, {[Cu(C(5)H(6)O(4))(ClO(4))(C(16)H(22)N(4))]ClO(4)·2H(2)O}(n), square-pyramidally coordinated Cu atoms with perchlorate and dimethyl­malonate ligands are connected into cationic sinusoidal coordination polymer chains by doubly protonated bis­(3-pyridylmeth­yl)piperazine (3-bpmp...

Descripción completa

Detalles Bibliográficos
Autores principales: Farnum, Gregory A., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959823/
https://www.ncbi.nlm.nih.gov/pubmed/21581141
http://dx.doi.org/10.1107/S1600536808036490
_version_ 1782188591912321024
author Farnum, Gregory A.
LaDuca, Robert L.
author_facet Farnum, Gregory A.
LaDuca, Robert L.
author_sort Farnum, Gregory A.
collection PubMed
description In the title compound, {[Cu(C(5)H(6)O(4))(ClO(4))(C(16)H(22)N(4))]ClO(4)·2H(2)O}(n), square-pyramidally coordinated Cu atoms with perchlorate and dimethyl­malonate ligands are connected into cationic sinusoidal coordination polymer chains by doubly protonated bis­(3-pyridylmeth­yl)piperazine (3-bpmp) ligands. The chains aggregate into pseudo-layers parallel to the (101) crystal planes by N—H⋯O hydrogen bonding. Unligated perchlorate anions and water mol­ecules of crystallization provide additional hydrogen bonding between pseudo-layers.
format Text
id pubmed-2959823
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29598232010-12-30 catena-Poly[[[(dimethyl­malonato-κ(2) O:O′)(perchlorato-κO)copper(II)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) N (1′):N (4′)] perchlorate dihydrate] Farnum, Gregory A. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(5)H(6)O(4))(ClO(4))(C(16)H(22)N(4))]ClO(4)·2H(2)O}(n), square-pyramidally coordinated Cu atoms with perchlorate and dimethyl­malonate ligands are connected into cationic sinusoidal coordination polymer chains by doubly protonated bis­(3-pyridylmeth­yl)piperazine (3-bpmp) ligands. The chains aggregate into pseudo-layers parallel to the (101) crystal planes by N—H⋯O hydrogen bonding. Unligated perchlorate anions and water mol­ecules of crystallization provide additional hydrogen bonding between pseudo-layers. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959823/ /pubmed/21581141 http://dx.doi.org/10.1107/S1600536808036490 Text en © Farnum and LaDuca 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Farnum, Gregory A.
LaDuca, Robert L.
catena-Poly[[[(dimethyl­malonato-κ(2) O:O′)(perchlorato-κO)copper(II)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) N (1′):N (4′)] perchlorate dihydrate]
title catena-Poly[[[(dimethyl­malonato-κ(2) O:O′)(perchlorato-κO)copper(II)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) N (1′):N (4′)] perchlorate dihydrate]
title_full catena-Poly[[[(dimethyl­malonato-κ(2) O:O′)(perchlorato-κO)copper(II)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) N (1′):N (4′)] perchlorate dihydrate]
title_fullStr catena-Poly[[[(dimethyl­malonato-κ(2) O:O′)(perchlorato-κO)copper(II)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) N (1′):N (4′)] perchlorate dihydrate]
title_full_unstemmed catena-Poly[[[(dimethyl­malonato-κ(2) O:O′)(perchlorato-κO)copper(II)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) N (1′):N (4′)] perchlorate dihydrate]
title_short catena-Poly[[[(dimethyl­malonato-κ(2) O:O′)(perchlorato-κO)copper(II)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) N (1′):N (4′)] perchlorate dihydrate]
title_sort catena-poly[[[(dimethyl­malonato-κ(2) o:o′)(perchlorato-κo)copper(ii)]-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ(2) n (1′):n (4′)] perchlorate dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959823/
https://www.ncbi.nlm.nih.gov/pubmed/21581141
http://dx.doi.org/10.1107/S1600536808036490
work_keys_str_mv AT farnumgregorya catenapolydimethylmalonatok2ooperchloratokocopperiimbis3pyridylmethylpiperazinediiumk2n1n4perchloratedihydrate
AT laducarobertl catenapolydimethylmalonatok2ooperchloratokocopperiimbis3pyridylmethylpiperazinediiumk2n1n4perchloratedihydrate

Ejemplares similares