r-2,c-6-Bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one

The asymmetric unit of the title compound, C(21)H(25)NO(3), contains two crystallographically independent mol­ecules (A and B). In both mol­ecules, the piperidine ring adopts a chair conformation, with the methoxy­phenyl rings attached equatorially. The dihedral angle between the two benzene rings i...

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Detalles Bibliográficos
Autores principales: Ponnuswamy, S., Mohanraj, V., Gayathri, P., Thiruvalluvar, A., Butcher, R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959826/
https://www.ncbi.nlm.nih.gov/pubmed/21581303
http://dx.doi.org/10.1107/S1600536808036830
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author Ponnuswamy, S.
Mohanraj, V.
Gayathri, P.
Thiruvalluvar, A.
Butcher, R. J.
author_facet Ponnuswamy, S.
Mohanraj, V.
Gayathri, P.
Thiruvalluvar, A.
Butcher, R. J.
author_sort Ponnuswamy, S.
collection PubMed
description The asymmetric unit of the title compound, C(21)H(25)NO(3), contains two crystallographically independent mol­ecules (A and B). In both mol­ecules, the piperidine ring adopts a chair conformation, with the methoxy­phenyl rings attached equatorially. The dihedral angle between the two benzene rings in mol­ecule A is 73.79 (8)°; the corresponding value in mol­ecule B is 77.71 (8)°. The mol­ecules are linked by N—H⋯O hydrogen bonds. In addition, C—H⋯π inter­actions are also found in the crystal structure.
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spelling pubmed-29598262010-12-30 r-2,c-6-Bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one Ponnuswamy, S. Mohanraj, V. Gayathri, P. Thiruvalluvar, A. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(25)NO(3), contains two crystallographically independent mol­ecules (A and B). In both mol­ecules, the piperidine ring adopts a chair conformation, with the methoxy­phenyl rings attached equatorially. The dihedral angle between the two benzene rings in mol­ecule A is 73.79 (8)°; the corresponding value in mol­ecule B is 77.71 (8)°. The mol­ecules are linked by N—H⋯O hydrogen bonds. In addition, C—H⋯π inter­actions are also found in the crystal structure. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959826/ /pubmed/21581303 http://dx.doi.org/10.1107/S1600536808036830 Text en © Ponnuswamy et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ponnuswamy, S.
Mohanraj, V.
Gayathri, P.
Thiruvalluvar, A.
Butcher, R. J.
r-2,c-6-Bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title r-2,c-6-Bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_full r-2,c-6-Bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_fullStr r-2,c-6-Bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_full_unstemmed r-2,c-6-Bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_short r-2,c-6-Bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
title_sort r-2,c-6-bis(4-methoxy­phen­yl)-c-3,t-3-dimethyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959826/
https://www.ncbi.nlm.nih.gov/pubmed/21581303
http://dx.doi.org/10.1107/S1600536808036830
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AT thiruvalluvara r2c6bis4methoxyphenylc3t3dimethylpiperidin4one
AT butcherrj r2c6bis4methoxyphenylc3t3dimethylpiperidin4one

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