Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V)

In the title compound, [Sb(C(6)H(5))(3)(C(6)H(3)BrNO(2))(2)], the Sb center has a distorted trigonal–bipyramidal geometry, with two carboxyl­ate O atoms of two 5-bromo­pyridine-2-carboxyl­ate ligands in equatorial positions and three phenyl ligands in axial positions. The crystal structure is stabil...

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Detalles Bibliográficos
Autores principales: Quan, Li, Yin, Handong, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959827/
https://www.ncbi.nlm.nih.gov/pubmed/21581123
http://dx.doi.org/10.1107/S1600536808033783
Descripción
Sumario:In the title compound, [Sb(C(6)H(5))(3)(C(6)H(3)BrNO(2))(2)], the Sb center has a distorted trigonal–bipyramidal geometry, with two carboxyl­ate O atoms of two 5-bromo­pyridine-2-carboxyl­ate ligands in equatorial positions and three phenyl ligands in axial positions. The crystal structure is stabilized by C—H⋯Br hydrogen bonds and inter­molecular C—Br⋯π inter­actions [C⋯π = 3.57 (1) Å].

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