Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V)

In the title compound, [Sb(C(6)H(5))(3)(C(6)H(3)BrNO(2))(2)], the Sb center has a distorted trigonal–bipyramidal geometry, with two carboxyl­ate O atoms of two 5-bromo­pyridine-2-carboxyl­ate ligands in equatorial positions and three phenyl ligands in axial positions. The crystal structure is stabil...

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Detalles Bibliográficos
Autores principales: Quan, Li, Yin, Handong, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959827/
https://www.ncbi.nlm.nih.gov/pubmed/21581123
http://dx.doi.org/10.1107/S1600536808033783
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author Quan, Li
Yin, Handong
Wang, Daqi
author_facet Quan, Li
Yin, Handong
Wang, Daqi
author_sort Quan, Li
collection PubMed
description In the title compound, [Sb(C(6)H(5))(3)(C(6)H(3)BrNO(2))(2)], the Sb center has a distorted trigonal–bipyramidal geometry, with two carboxyl­ate O atoms of two 5-bromo­pyridine-2-carboxyl­ate ligands in equatorial positions and three phenyl ligands in axial positions. The crystal structure is stabilized by C—H⋯Br hydrogen bonds and inter­molecular C—Br⋯π inter­actions [C⋯π = 3.57 (1) Å].
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spelling pubmed-29598272010-12-30 Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V) Quan, Li Yin, Handong Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sb(C(6)H(5))(3)(C(6)H(3)BrNO(2))(2)], the Sb center has a distorted trigonal–bipyramidal geometry, with two carboxyl­ate O atoms of two 5-bromo­pyridine-2-carboxyl­ate ligands in equatorial positions and three phenyl ligands in axial positions. The crystal structure is stabilized by C—H⋯Br hydrogen bonds and inter­molecular C—Br⋯π inter­actions [C⋯π = 3.57 (1) Å]. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959827/ /pubmed/21581123 http://dx.doi.org/10.1107/S1600536808033783 Text en © Quan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Quan, Li
Yin, Handong
Wang, Daqi
Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V)
title Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V)
title_full Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V)
title_fullStr Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V)
title_full_unstemmed Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V)
title_short Bis(5-bromo­pyridine-2-carboxyl­ato-κO)triphenyl­anti­mony(V)
title_sort bis(5-bromo­pyridine-2-carboxyl­ato-κo)triphenyl­anti­mony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959827/
https://www.ncbi.nlm.nih.gov/pubmed/21581123
http://dx.doi.org/10.1107/S1600536808033783
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AT yinhandong bis5bromopyridine2carboxylatokotriphenylantimonyv
AT wangdaqi bis5bromopyridine2carboxylatokotriphenylantimonyv

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