(R (p))-1-{(R)-(Dimethylamino)[2-(diphenylphosphanyl)phenyl]methyl}-2-(diphenylphosphanyl)ferrocene chloroform solvate
The absolute configuration of the title molecule, [Fe(C(5)H(5))(C(38)H(34)NP(2))]·CHCl(3), is R,R (p). The molecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007 ▶). J. Org. Chem. 72, 1514–1517], but some torsion angles about the P—C(ph...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959829/ https://www.ncbi.nlm.nih.gov/pubmed/21581228 http://dx.doi.org/10.1107/S160053680803955X |
Sumario: | The absolute configuration of the title molecule, [Fe(C(5)H(5))(C(38)H(34)NP(2))]·CHCl(3), is R,R (p). The molecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007 ▶). J. Org. Chem. 72, 1514–1517], but some torsion angles about the P—C(phenyl) bonds differ by up to 25°. The P atoms and the N atom have a distorted trigonal-pyramidal geometry. The chloroform solvate group donates a C—H⋯π bond to the central benzene ring and is also involved in six intermolecular C—H⋯Cl contacts with H⋯Cl distances between 2.96 and 3.13 Å. |
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