(R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate

The absolute configuration of the title mol­ecule, [Fe(C(5)H(5))(C(38)H(34)NP(2))]·CHCl(3), is R,R (p). The mol­ecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007 ▶). J. Org. Chem. 72, 1514–1517], but some torsion angles about the P—C(ph...

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Detalles Bibliográficos
Autores principales: Bats, Jan W., Rivas Nass, Andreas, Doppiu, Angelino, Karch, Ralf, Hashmi, A. Stephen K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959829/
https://www.ncbi.nlm.nih.gov/pubmed/21581228
http://dx.doi.org/10.1107/S160053680803955X
Descripción
Sumario:The absolute configuration of the title mol­ecule, [Fe(C(5)H(5))(C(38)H(34)NP(2))]·CHCl(3), is R,R (p). The mol­ecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007 ▶). J. Org. Chem. 72, 1514–1517], but some torsion angles about the P—C(phen­yl) bonds differ by up to 25°. The P atoms and the N atom have a distorted trigonal-pyramidal geometry. The chloro­form solvate group donates a C—H⋯π bond to the central benzene ring and is also involved in six inter­molecular C—H⋯Cl contacts with H⋯Cl distances between 2.96 and 3.13 Å.