(R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate

The absolute configuration of the title mol­ecule, [Fe(C(5)H(5))(C(38)H(34)NP(2))]·CHCl(3), is R,R (p). The mol­ecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007 ▶). J. Org. Chem. 72, 1514–1517], but some torsion angles about the P—C(ph...

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Autores principales: Bats, Jan W., Rivas Nass, Andreas, Doppiu, Angelino, Karch, Ralf, Hashmi, A. Stephen K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959829/
https://www.ncbi.nlm.nih.gov/pubmed/21581228
http://dx.doi.org/10.1107/S160053680803955X
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author Bats, Jan W.
Rivas Nass, Andreas
Doppiu, Angelino
Karch, Ralf
Hashmi, A. Stephen K.
author_facet Bats, Jan W.
Rivas Nass, Andreas
Doppiu, Angelino
Karch, Ralf
Hashmi, A. Stephen K.
author_sort Bats, Jan W.
collection PubMed
description The absolute configuration of the title mol­ecule, [Fe(C(5)H(5))(C(38)H(34)NP(2))]·CHCl(3), is R,R (p). The mol­ecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007 ▶). J. Org. Chem. 72, 1514–1517], but some torsion angles about the P—C(phen­yl) bonds differ by up to 25°. The P atoms and the N atom have a distorted trigonal-pyramidal geometry. The chloro­form solvate group donates a C—H⋯π bond to the central benzene ring and is also involved in six inter­molecular C—H⋯Cl contacts with H⋯Cl distances between 2.96 and 3.13 Å.
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spelling pubmed-29598292010-12-30 (R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate Bats, Jan W. Rivas Nass, Andreas Doppiu, Angelino Karch, Ralf Hashmi, A. Stephen K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The absolute configuration of the title mol­ecule, [Fe(C(5)H(5))(C(38)H(34)NP(2))]·CHCl(3), is R,R (p). The mol­ecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007 ▶). J. Org. Chem. 72, 1514–1517], but some torsion angles about the P—C(phen­yl) bonds differ by up to 25°. The P atoms and the N atom have a distorted trigonal-pyramidal geometry. The chloro­form solvate group donates a C—H⋯π bond to the central benzene ring and is also involved in six inter­molecular C—H⋯Cl contacts with H⋯Cl distances between 2.96 and 3.13 Å. International Union of Crystallography 2008-11-29 /pmc/articles/PMC2959829/ /pubmed/21581228 http://dx.doi.org/10.1107/S160053680803955X Text en © Bats et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bats, Jan W.
Rivas Nass, Andreas
Doppiu, Angelino
Karch, Ralf
Hashmi, A. Stephen K.
(R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate
title (R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate
title_full (R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate
title_fullStr (R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate
title_full_unstemmed (R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate
title_short (R (p))-1-{(R)-(Dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate
title_sort (r (p))-1-{(r)-(dimethyl­amino)[2-(diphenyl­phosphan­yl)phen­yl]methyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959829/
https://www.ncbi.nlm.nih.gov/pubmed/21581228
http://dx.doi.org/10.1107/S160053680803955X
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AT doppiuangelino rp1rdimethylamino2diphenylphosphanylphenylmethyl2diphenylphosphanylferrocenechloroformsolvate
AT karchralf rp1rdimethylamino2diphenylphosphanylphenylmethyl2diphenylphosphanylferrocenechloroformsolvate
AT hashmiastephenk rp1rdimethylamino2diphenylphosphanylphenylmethyl2diphenylphosphanylferrocenechloroformsolvate

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