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catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]

The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydro­thermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two o...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Mu, Chunhua, Kong, Binbin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959831/
https://www.ncbi.nlm.nih.gov/pubmed/21581114
http://dx.doi.org/10.1107/S1600536808026354
Descripción
Sumario:The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydro­thermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two of which bridge Nd(III) atoms, and by two O atoms from a further two bridging acrylate ligands. The other Nd(III) atom is coordinated by two bidentate acrylate ligands, two O atoms from bridging acrylate ligands, and three water mol­ecules. Extensive hydrogen bonding between the coordinated and uncoordin­ated water mol­ecules and the O atoms of the acrylate ligands link the coordination polymers into a three-dimensional network.