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catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]
The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydrothermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two o...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959831/ https://www.ncbi.nlm.nih.gov/pubmed/21581114 http://dx.doi.org/10.1107/S1600536808026354 |
Sumario: | The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydrothermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two of which bridge Nd(III) atoms, and by two O atoms from a further two bridging acrylate ligands. The other Nd(III) atom is coordinated by two bidentate acrylate ligands, two O atoms from bridging acrylate ligands, and three water molecules. Extensive hydrogen bonding between the coordinated and uncoordinated water molecules and the O atoms of the acrylate ligands link the coordination polymers into a three-dimensional network. |
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