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catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]

The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydro­thermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two o...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Mu, Chunhua, Kong, Binbin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959831/
https://www.ncbi.nlm.nih.gov/pubmed/21581114
http://dx.doi.org/10.1107/S1600536808026354
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author Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_facet Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_sort Hao, Lujiang
collection PubMed
description The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydro­thermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two of which bridge Nd(III) atoms, and by two O atoms from a further two bridging acrylate ligands. The other Nd(III) atom is coordinated by two bidentate acrylate ligands, two O atoms from bridging acrylate ligands, and three water mol­ecules. Extensive hydrogen bonding between the coordinated and uncoordin­ated water mol­ecules and the O atoms of the acrylate ligands link the coordination polymers into a three-dimensional network.
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spelling pubmed-29598312010-12-30 catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate] Hao, Lujiang Mu, Chunhua Kong, Binbin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydro­thermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two of which bridge Nd(III) atoms, and by two O atoms from a further two bridging acrylate ligands. The other Nd(III) atom is coordinated by two bidentate acrylate ligands, two O atoms from bridging acrylate ligands, and three water mol­ecules. Extensive hydrogen bonding between the coordinated and uncoordin­ated water mol­ecules and the O atoms of the acrylate ligands link the coordination polymers into a three-dimensional network. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959831/ /pubmed/21581114 http://dx.doi.org/10.1107/S1600536808026354 Text en © Hao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Lujiang
Mu, Chunhua
Kong, Binbin
catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]
title catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]
title_full catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]
title_fullStr catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]
title_full_unstemmed catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]
title_short catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaqua­neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]
title_sort catena-poly[[[diacrylato-κ(4) o,o′-neodymium(iii)]-di-μ-acrylato-κ(3) o,o′:o′;κ(3) o:o,o′-[triaqua­neodymium(iii)]-di-μ-acrylato-κ(3) o,o′:o′;κ(3) o:o,o′] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959831/
https://www.ncbi.nlm.nih.gov/pubmed/21581114
http://dx.doi.org/10.1107/S1600536808026354
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