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catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate]
The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydrothermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two o...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959831/ https://www.ncbi.nlm.nih.gov/pubmed/21581114 http://dx.doi.org/10.1107/S1600536808026354 |
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author | Hao, Lujiang Mu, Chunhua Kong, Binbin |
author_facet | Hao, Lujiang Mu, Chunhua Kong, Binbin |
author_sort | Hao, Lujiang |
collection | PubMed |
description | The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydrothermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two of which bridge Nd(III) atoms, and by two O atoms from a further two bridging acrylate ligands. The other Nd(III) atom is coordinated by two bidentate acrylate ligands, two O atoms from bridging acrylate ligands, and three water molecules. Extensive hydrogen bonding between the coordinated and uncoordinated water molecules and the O atoms of the acrylate ligands link the coordination polymers into a three-dimensional network. |
format | Text |
id | pubmed-2959831 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598312010-12-30 catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate] Hao, Lujiang Mu, Chunhua Kong, Binbin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]·3H(2)O}(n), was synthesized by hydrothermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two of which bridge Nd(III) atoms, and by two O atoms from a further two bridging acrylate ligands. The other Nd(III) atom is coordinated by two bidentate acrylate ligands, two O atoms from bridging acrylate ligands, and three water molecules. Extensive hydrogen bonding between the coordinated and uncoordinated water molecules and the O atoms of the acrylate ligands link the coordination polymers into a three-dimensional network. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959831/ /pubmed/21581114 http://dx.doi.org/10.1107/S1600536808026354 Text en © Hao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hao, Lujiang Mu, Chunhua Kong, Binbin catena-Poly[[[diacrylato-κ(4) O,O′-neodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3) O,O′:O′;κ(3) O:O,O′] trihydrate] |
title |
catena-Poly[[[diacrylato-κ(4)
O,O′-neodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′] trihydrate] |
title_full |
catena-Poly[[[diacrylato-κ(4)
O,O′-neodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′] trihydrate] |
title_fullStr |
catena-Poly[[[diacrylato-κ(4)
O,O′-neodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′] trihydrate] |
title_full_unstemmed |
catena-Poly[[[diacrylato-κ(4)
O,O′-neodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′] trihydrate] |
title_short |
catena-Poly[[[diacrylato-κ(4)
O,O′-neodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′-[triaquaneodymium(III)]-di-μ-acrylato-κ(3)
O,O′:O′;κ(3)
O:O,O′] trihydrate] |
title_sort | catena-poly[[[diacrylato-κ(4)
o,o′-neodymium(iii)]-di-μ-acrylato-κ(3)
o,o′:o′;κ(3)
o:o,o′-[triaquaneodymium(iii)]-di-μ-acrylato-κ(3)
o,o′:o′;κ(3)
o:o,o′] trihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959831/ https://www.ncbi.nlm.nih.gov/pubmed/21581114 http://dx.doi.org/10.1107/S1600536808026354 |
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