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(4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II)

The Cd(II) atom in the title compound, [Cd(C(12)H(27)O(3)SSi)(2)(C(4)H(6)N(2)O)], is penta­coordinated by two O and two S atoms from the O,S-chelating silanethiol­ate residue and one N from the 4-hydroxy­methyl­imidazole ligand and shows a strongly distorted trigonal-bipyramidal geometry. The title...

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Detalles Bibliográficos
Autores principales: Dołęga, Anna, Baranowska, Katarzyna, Jarząbek, Żaneta
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959838/
https://www.ncbi.nlm.nih.gov/pubmed/21581133
http://dx.doi.org/10.1107/S1600536808035642
Descripción
Sumario:The Cd(II) atom in the title compound, [Cd(C(12)H(27)O(3)SSi)(2)(C(4)H(6)N(2)O)], is penta­coordinated by two O and two S atoms from the O,S-chelating silanethiol­ate residue and one N from the 4-hydroxy­methyl­imidazole ligand and shows a strongly distorted trigonal-bipyramidal geometry. The title complex is isostructural with its zinc analog. The hydroxy group of the ligand is involved in intra­molecular O—H⋯S hydrogen bonding and also acts as an acceptor in the formation of an inter­molecular N—H⋯O hydrogen bond, which links mol­ecules of the complex into zigzag chains parallel to the b axis. One of the tert-butyl groups is disordered over two orientations with occupancies of 0.557 (12):0.443 (12).