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(4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II)

The Cd(II) atom in the title compound, [Cd(C(12)H(27)O(3)SSi)(2)(C(4)H(6)N(2)O)], is penta­coordinated by two O and two S atoms from the O,S-chelating silanethiol­ate residue and one N from the 4-hydroxy­methyl­imidazole ligand and shows a strongly distorted trigonal-bipyramidal geometry. The title...

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Detalles Bibliográficos
Autores principales: Dołęga, Anna, Baranowska, Katarzyna, Jarząbek, Żaneta
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959838/
https://www.ncbi.nlm.nih.gov/pubmed/21581133
http://dx.doi.org/10.1107/S1600536808035642
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author Dołęga, Anna
Baranowska, Katarzyna
Jarząbek, Żaneta
author_facet Dołęga, Anna
Baranowska, Katarzyna
Jarząbek, Żaneta
author_sort Dołęga, Anna
collection PubMed
description The Cd(II) atom in the title compound, [Cd(C(12)H(27)O(3)SSi)(2)(C(4)H(6)N(2)O)], is penta­coordinated by two O and two S atoms from the O,S-chelating silanethiol­ate residue and one N from the 4-hydroxy­methyl­imidazole ligand and shows a strongly distorted trigonal-bipyramidal geometry. The title complex is isostructural with its zinc analog. The hydroxy group of the ligand is involved in intra­molecular O—H⋯S hydrogen bonding and also acts as an acceptor in the formation of an inter­molecular N—H⋯O hydrogen bond, which links mol­ecules of the complex into zigzag chains parallel to the b axis. One of the tert-butyl groups is disordered over two orientations with occupancies of 0.557 (12):0.443 (12).
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spelling pubmed-29598382010-12-30 (4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II) Dołęga, Anna Baranowska, Katarzyna Jarząbek, Żaneta Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cd(II) atom in the title compound, [Cd(C(12)H(27)O(3)SSi)(2)(C(4)H(6)N(2)O)], is penta­coordinated by two O and two S atoms from the O,S-chelating silanethiol­ate residue and one N from the 4-hydroxy­methyl­imidazole ligand and shows a strongly distorted trigonal-bipyramidal geometry. The title complex is isostructural with its zinc analog. The hydroxy group of the ligand is involved in intra­molecular O—H⋯S hydrogen bonding and also acts as an acceptor in the formation of an inter­molecular N—H⋯O hydrogen bond, which links mol­ecules of the complex into zigzag chains parallel to the b axis. One of the tert-butyl groups is disordered over two orientations with occupancies of 0.557 (12):0.443 (12). International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959838/ /pubmed/21581133 http://dx.doi.org/10.1107/S1600536808035642 Text en © Dołęga et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dołęga, Anna
Baranowska, Katarzyna
Jarząbek, Żaneta
(4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II)
title (4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II)
title_full (4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II)
title_fullStr (4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II)
title_full_unstemmed (4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II)
title_short (4-Hydroxy­methyl-1H-imidazole-κN (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) O,S)cadmium(II)
title_sort (4-hydroxy­methyl-1h-imidazole-κn (3))bis­(tri-tert-butoxy­silanethiol­ato-κ(2) o,s)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959838/
https://www.ncbi.nlm.nih.gov/pubmed/21581133
http://dx.doi.org/10.1107/S1600536808035642
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