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(4-Hydroxymethyl-1H-imidazole-κN (3))bis(tri-tert-butoxysilanethiolato-κ(2) O,S)cadmium(II)
The Cd(II) atom in the title compound, [Cd(C(12)H(27)O(3)SSi)(2)(C(4)H(6)N(2)O)], is pentacoordinated by two O and two S atoms from the O,S-chelating silanethiolate residue and one N from the 4-hydroxymethylimidazole ligand and shows a strongly distorted trigonal-bipyramidal geometry. The title...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959838/ https://www.ncbi.nlm.nih.gov/pubmed/21581133 http://dx.doi.org/10.1107/S1600536808035642 |
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author | Dołęga, Anna Baranowska, Katarzyna Jarząbek, Żaneta |
author_facet | Dołęga, Anna Baranowska, Katarzyna Jarząbek, Żaneta |
author_sort | Dołęga, Anna |
collection | PubMed |
description | The Cd(II) atom in the title compound, [Cd(C(12)H(27)O(3)SSi)(2)(C(4)H(6)N(2)O)], is pentacoordinated by two O and two S atoms from the O,S-chelating silanethiolate residue and one N from the 4-hydroxymethylimidazole ligand and shows a strongly distorted trigonal-bipyramidal geometry. The title complex is isostructural with its zinc analog. The hydroxy group of the ligand is involved in intramolecular O—H⋯S hydrogen bonding and also acts as an acceptor in the formation of an intermolecular N—H⋯O hydrogen bond, which links molecules of the complex into zigzag chains parallel to the b axis. One of the tert-butyl groups is disordered over two orientations with occupancies of 0.557 (12):0.443 (12). |
format | Text |
id | pubmed-2959838 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598382010-12-30 (4-Hydroxymethyl-1H-imidazole-κN (3))bis(tri-tert-butoxysilanethiolato-κ(2) O,S)cadmium(II) Dołęga, Anna Baranowska, Katarzyna Jarząbek, Żaneta Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cd(II) atom in the title compound, [Cd(C(12)H(27)O(3)SSi)(2)(C(4)H(6)N(2)O)], is pentacoordinated by two O and two S atoms from the O,S-chelating silanethiolate residue and one N from the 4-hydroxymethylimidazole ligand and shows a strongly distorted trigonal-bipyramidal geometry. The title complex is isostructural with its zinc analog. The hydroxy group of the ligand is involved in intramolecular O—H⋯S hydrogen bonding and also acts as an acceptor in the formation of an intermolecular N—H⋯O hydrogen bond, which links molecules of the complex into zigzag chains parallel to the b axis. One of the tert-butyl groups is disordered over two orientations with occupancies of 0.557 (12):0.443 (12). International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959838/ /pubmed/21581133 http://dx.doi.org/10.1107/S1600536808035642 Text en © Dołęga et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dołęga, Anna Baranowska, Katarzyna Jarząbek, Żaneta (4-Hydroxymethyl-1H-imidazole-κN (3))bis(tri-tert-butoxysilanethiolato-κ(2) O,S)cadmium(II) |
title | (4-Hydroxymethyl-1H-imidazole-κN
(3))bis(tri-tert-butoxysilanethiolato-κ(2)
O,S)cadmium(II) |
title_full | (4-Hydroxymethyl-1H-imidazole-κN
(3))bis(tri-tert-butoxysilanethiolato-κ(2)
O,S)cadmium(II) |
title_fullStr | (4-Hydroxymethyl-1H-imidazole-κN
(3))bis(tri-tert-butoxysilanethiolato-κ(2)
O,S)cadmium(II) |
title_full_unstemmed | (4-Hydroxymethyl-1H-imidazole-κN
(3))bis(tri-tert-butoxysilanethiolato-κ(2)
O,S)cadmium(II) |
title_short | (4-Hydroxymethyl-1H-imidazole-κN
(3))bis(tri-tert-butoxysilanethiolato-κ(2)
O,S)cadmium(II) |
title_sort | (4-hydroxymethyl-1h-imidazole-κn
(3))bis(tri-tert-butoxysilanethiolato-κ(2)
o,s)cadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959838/ https://www.ncbi.nlm.nih.gov/pubmed/21581133 http://dx.doi.org/10.1107/S1600536808035642 |
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