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Tetrakis(3,5-dimethyl-1H-pyrazole-κN (2))(nitrato-κ(2) O,O′)cadmium(II) nitrate
The title compound, [Cd(NO(3))(C(5)H(8)N(2))(4)]NO(3), was prepared by reaction of cadmium nitrate and 3,5-dimethylpyrazole in ethanol solution. The Cd atom adopts a distorted cis-CdO(2)N(4) octahedral geometry involving four dimethylpyrazole molecules and one bidentate nitrate anion. The molecul...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959841/ https://www.ncbi.nlm.nih.gov/pubmed/21581147 http://dx.doi.org/10.1107/S160053680803626X |
| _version_ | 1782188596341506048 |
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| author | Wang, Su-Qing Jian, Fang-Fang |
| author_facet | Wang, Su-Qing Jian, Fang-Fang |
| author_sort | Wang, Su-Qing |
| collection | PubMed |
| description | The title compound, [Cd(NO(3))(C(5)H(8)N(2))(4)]NO(3), was prepared by reaction of cadmium nitrate and 3,5-dimethylpyrazole in ethanol solution. The Cd atom adopts a distorted cis-CdO(2)N(4) octahedral geometry involving four dimethylpyrazole molecules and one bidentate nitrate anion. The molecular structure and packing are stabilized by N—H⋯O and C—H⋯O inter- and intramolecular hydrogen-bonding interactions. |
| format | Text |
| id | pubmed-2959841 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29598412010-12-30 Tetrakis(3,5-dimethyl-1H-pyrazole-κN (2))(nitrato-κ(2) O,O′)cadmium(II) nitrate Wang, Su-Qing Jian, Fang-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(NO(3))(C(5)H(8)N(2))(4)]NO(3), was prepared by reaction of cadmium nitrate and 3,5-dimethylpyrazole in ethanol solution. The Cd atom adopts a distorted cis-CdO(2)N(4) octahedral geometry involving four dimethylpyrazole molecules and one bidentate nitrate anion. The molecular structure and packing are stabilized by N—H⋯O and C—H⋯O inter- and intramolecular hydrogen-bonding interactions. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959841/ /pubmed/21581147 http://dx.doi.org/10.1107/S160053680803626X Text en © Wang and Jian 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Su-Qing Jian, Fang-Fang Tetrakis(3,5-dimethyl-1H-pyrazole-κN (2))(nitrato-κ(2) O,O′)cadmium(II) nitrate |
| title | Tetrakis(3,5-dimethyl-1H-pyrazole-κN
(2))(nitrato-κ(2)
O,O′)cadmium(II) nitrate |
| title_full | Tetrakis(3,5-dimethyl-1H-pyrazole-κN
(2))(nitrato-κ(2)
O,O′)cadmium(II) nitrate |
| title_fullStr | Tetrakis(3,5-dimethyl-1H-pyrazole-κN
(2))(nitrato-κ(2)
O,O′)cadmium(II) nitrate |
| title_full_unstemmed | Tetrakis(3,5-dimethyl-1H-pyrazole-κN
(2))(nitrato-κ(2)
O,O′)cadmium(II) nitrate |
| title_short | Tetrakis(3,5-dimethyl-1H-pyrazole-κN
(2))(nitrato-κ(2)
O,O′)cadmium(II) nitrate |
| title_sort | tetrakis(3,5-dimethyl-1h-pyrazole-κn
(2))(nitrato-κ(2)
o,o′)cadmium(ii) nitrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959841/ https://www.ncbi.nlm.nih.gov/pubmed/21581147 http://dx.doi.org/10.1107/S160053680803626X |
| work_keys_str_mv | AT wangsuqing tetrakis35dimethyl1hpyrazolekn2nitratok2oocadmiumiinitrate AT jianfangfang tetrakis35dimethyl1hpyrazolekn2nitratok2oocadmiumiinitrate |