Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(II)]

In the title compound, [Co(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)], the Co(II) atom is coordinated by two N atoms from one 2,2′-bipyridine ligand and two O atoms from two biphenyl-2,2′-dicarboxyl­ate (2,2′-dpa) ligands in a distorted planar geometry. Longer Co—O contacts [2.437 (3) and 2.552 (3) Å]...

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Detalles Bibliográficos
Autores principales: An, Zhe, Niu, Xian-Chun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959843/
https://www.ncbi.nlm.nih.gov/pubmed/21581165
http://dx.doi.org/10.1107/S1600536808037288
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author An, Zhe
Niu, Xian-Chun
author_facet An, Zhe
Niu, Xian-Chun
author_sort An, Zhe
collection PubMed
description In the title compound, [Co(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)], the Co(II) atom is coordinated by two N atoms from one 2,2′-bipyridine ligand and two O atoms from two biphenyl-2,2′-dicarboxyl­ate (2,2′-dpa) ligands in a distorted planar geometry. Longer Co—O contacts [2.437 (3) and 2.552 (3) Å] are formed to the second O atom of each coordinated carboxyl­ate group so that these groups approximate a bidentate coordination mode and the coordination geometry around Co(II) approaches distorted octa­hedral. The 2,2′-dpa ligands bridge two Co(II) atoms, forming a cyclic dinuclear complex around a centre of inversion.
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spelling pubmed-29598432010-12-30 Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(II)] An, Zhe Niu, Xian-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)], the Co(II) atom is coordinated by two N atoms from one 2,2′-bipyridine ligand and two O atoms from two biphenyl-2,2′-dicarboxyl­ate (2,2′-dpa) ligands in a distorted planar geometry. Longer Co—O contacts [2.437 (3) and 2.552 (3) Å] are formed to the second O atom of each coordinated carboxyl­ate group so that these groups approximate a bidentate coordination mode and the coordination geometry around Co(II) approaches distorted octa­hedral. The 2,2′-dpa ligands bridge two Co(II) atoms, forming a cyclic dinuclear complex around a centre of inversion. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959843/ /pubmed/21581165 http://dx.doi.org/10.1107/S1600536808037288 Text en © An and Niu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
An, Zhe
Niu, Xian-Chun
Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(II)]
title Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(II)]
title_full Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(II)]
title_fullStr Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(II)]
title_full_unstemmed Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(II)]
title_short Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(II)]
title_sort bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[(2,2′-bipyridine)cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959843/
https://www.ncbi.nlm.nih.gov/pubmed/21581165
http://dx.doi.org/10.1107/S1600536808037288
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AT niuxianchun bismbiphenyl22dicarboxylatobis22bipyridinecobaltii

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