Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II)

The Schiff base 2-[(4-methyl­phen­yl)imino­meth­yl]-6-methoxy­phenol (HL) forms a complex with a Zn(2+) atom and two independent thio­cyanate ions, [Zn(NCS)(2)(C(15)H(15)NO(2))(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn(2+) atom. The proton...

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Detalles Bibliográficos
Autores principales: Li, Hua-Qiong, Xian, Hui-Duo, Liu, Jian-Feng, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959850/
https://www.ncbi.nlm.nih.gov/pubmed/21581116
http://dx.doi.org/10.1107/S1600536808035368
Descripción
Sumario:The Schiff base 2-[(4-methyl­phen­yl)imino­meth­yl]-6-methoxy­phenol (HL) forms a complex with a Zn(2+) atom and two independent thio­cyanate ions, [Zn(NCS)(2)(C(15)H(15)NO(2))(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn(2+) atom. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the phenoxide group. The Zn atom is also coordinated by two N atoms of two thio­cyanate ligands. The coordination environment of the Zn atom is distorted-tetra­hedral.

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