Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II)

The Schiff base 2-[(4-methyl­phen­yl)imino­meth­yl]-6-methoxy­phenol (HL) forms a complex with a Zn(2+) atom and two independent thio­cyanate ions, [Zn(NCS)(2)(C(15)H(15)NO(2))(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn(2+) atom. The proton...

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Detalles Bibliográficos
Autores principales: Li, Hua-Qiong, Xian, Hui-Duo, Liu, Jian-Feng, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959850/
https://www.ncbi.nlm.nih.gov/pubmed/21581116
http://dx.doi.org/10.1107/S1600536808035368
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author Li, Hua-Qiong
Xian, Hui-Duo
Liu, Jian-Feng
Zhao, Guo-Liang
author_facet Li, Hua-Qiong
Xian, Hui-Duo
Liu, Jian-Feng
Zhao, Guo-Liang
author_sort Li, Hua-Qiong
collection PubMed
description The Schiff base 2-[(4-methyl­phen­yl)imino­meth­yl]-6-methoxy­phenol (HL) forms a complex with a Zn(2+) atom and two independent thio­cyanate ions, [Zn(NCS)(2)(C(15)H(15)NO(2))(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn(2+) atom. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the phenoxide group. The Zn atom is also coordinated by two N atoms of two thio­cyanate ligands. The coordination environment of the Zn atom is distorted-tetra­hedral.
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spelling pubmed-29598502010-12-30 Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II) Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Schiff base 2-[(4-methyl­phen­yl)imino­meth­yl]-6-methoxy­phenol (HL) forms a complex with a Zn(2+) atom and two independent thio­cyanate ions, [Zn(NCS)(2)(C(15)H(15)NO(2))(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn(2+) atom. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the phenoxide group. The Zn atom is also coordinated by two N atoms of two thio­cyanate ligands. The coordination environment of the Zn atom is distorted-tetra­hedral. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959850/ /pubmed/21581116 http://dx.doi.org/10.1107/S1600536808035368 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hua-Qiong
Xian, Hui-Duo
Liu, Jian-Feng
Zhao, Guo-Liang
Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II)
title Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II)
title_full Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II)
title_fullStr Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II)
title_full_unstemmed Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II)
title_short Bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κO (1)}bis­(thio­cyanato-κN)zinc(II)
title_sort bis{2-methoxy-6-[(4-methyl­phen­yl)iminiometh­yl]­phenolato-κo (1)}bis­(thio­cyanato-κn)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959850/
https://www.ncbi.nlm.nih.gov/pubmed/21581116
http://dx.doi.org/10.1107/S1600536808035368
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AT xianhuiduo bis2methoxy64methylphenyliminiomethylphenolatoko1bisthiocyanatoknzincii
AT liujianfeng bis2methoxy64methylphenyliminiomethylphenolatoko1bisthiocyanatoknzincii
AT zhaoguoliang bis2methoxy64methylphenyliminiomethylphenolatoko1bisthiocyanatoknzincii

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