2-r-(4-Chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2H-thio­pyran-4-one 1-oxide

The thio­pyran unit of the title mol­ecule, C(17)H(15)ClO(2)S, is in chair form. A crystallographic mirror plane bis­ects the mol­ecule, passing through the O=S and the opposite C=O atoms of the central ring, with statistical disorder of the Cl atom. The geometry around the S atom is tetra­hedral an...

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Autores principales: Thiruvalluvar, A., Balamurugan, S., Butcher, R. J., Pandiarajan, K., Devanathan, D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959857/
https://www.ncbi.nlm.nih.gov/pubmed/21581339
http://dx.doi.org/10.1107/S1600536808037355
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author Thiruvalluvar, A.
Balamurugan, S.
Butcher, R. J.
Pandiarajan, K.
Devanathan, D.
author_facet Thiruvalluvar, A.
Balamurugan, S.
Butcher, R. J.
Pandiarajan, K.
Devanathan, D.
author_sort Thiruvalluvar, A.
collection PubMed
description The thio­pyran unit of the title mol­ecule, C(17)H(15)ClO(2)S, is in chair form. A crystallographic mirror plane bis­ects the mol­ecule, passing through the O=S and the opposite C=O atoms of the central ring, with statistical disorder of the Cl atom. The geometry around the S atom is tetra­hedral and the carbonyl C is planar. The 4-chloro­phenyl group at the 2 position and the phenyl ring at the 6 position have equatorial orientations. Inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds are found in the crystal structure. In addition, there is a short O⋯C inter­molecular contact [2.970 (5) Å].
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spelling pubmed-29598572010-12-30 2-r-(4-Chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2H-thio­pyran-4-one 1-oxide Thiruvalluvar, A. Balamurugan, S. Butcher, R. J. Pandiarajan, K. Devanathan, D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The thio­pyran unit of the title mol­ecule, C(17)H(15)ClO(2)S, is in chair form. A crystallographic mirror plane bis­ects the mol­ecule, passing through the O=S and the opposite C=O atoms of the central ring, with statistical disorder of the Cl atom. The geometry around the S atom is tetra­hedral and the carbonyl C is planar. The 4-chloro­phenyl group at the 2 position and the phenyl ring at the 6 position have equatorial orientations. Inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds are found in the crystal structure. In addition, there is a short O⋯C inter­molecular contact [2.970 (5) Å]. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959857/ /pubmed/21581339 http://dx.doi.org/10.1107/S1600536808037355 Text en © Thiruvalluvar et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thiruvalluvar, A.
Balamurugan, S.
Butcher, R. J.
Pandiarajan, K.
Devanathan, D.
2-r-(4-Chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2H-thio­pyran-4-one 1-oxide
title 2-r-(4-Chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2H-thio­pyran-4-one 1-oxide
title_full 2-r-(4-Chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2H-thio­pyran-4-one 1-oxide
title_fullStr 2-r-(4-Chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2H-thio­pyran-4-one 1-oxide
title_full_unstemmed 2-r-(4-Chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2H-thio­pyran-4-one 1-oxide
title_short 2-r-(4-Chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2H-thio­pyran-4-one 1-oxide
title_sort 2-r-(4-chloro­phen­yl)-6-c-phenyl-3,4,5,6-tetra­hydro-2h-thio­pyran-4-one 1-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959857/
https://www.ncbi.nlm.nih.gov/pubmed/21581339
http://dx.doi.org/10.1107/S1600536808037355
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AT butcherrj 2r4chlorophenyl6cphenyl3456tetrahydro2hthiopyran4one1oxide
AT pandiarajank 2r4chlorophenyl6cphenyl3456tetrahydro2hthiopyran4one1oxide
AT devanathand 2r4chlorophenyl6cphenyl3456tetrahydro2hthiopyran4one1oxide

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