Cargando…
catena-Poly[[diaqua(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2) O:O′]
In the title compound, [Ni(C(14)H(8)O(4))(C(10)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is coordinated in a slightly distorted octahedral geometry by two water molecules, two N atoms from a 2,2′-bipyridine ligand and two O atoms from the carboxylate groups of two 2,2′-biphenyldicarboxylate (2,2...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959859/ https://www.ncbi.nlm.nih.gov/pubmed/21581159 http://dx.doi.org/10.1107/S1600536808036866 |
Sumario: | In the title compound, [Ni(C(14)H(8)O(4))(C(10)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is coordinated in a slightly distorted octahedral geometry by two water molecules, two N atoms from a 2,2′-bipyridine ligand and two O atoms from the carboxylate groups of two 2,2′-biphenyldicarboxylate (2,2′-dpa) ligands. The 2,2′-dpa ligand acts as a bridge between neighbouring Ni(II) atoms, forming one-dimensional coordination polymers along [100]. The coordinated water molecules form hydrogen bonds to the carboxylate O atoms of 2,2′-dpa within the same coordination polymer, and one O—H⋯π interaction is also formed to 2,2′-dpa. |
---|