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catena-Poly[[diaqua(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2) O:O′]
In the title compound, [Ni(C(14)H(8)O(4))(C(10)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is coordinated in a slightly distorted octahedral geometry by two water molecules, two N atoms from a 2,2′-bipyridine ligand and two O atoms from the carboxylate groups of two 2,2′-biphenyldicarboxylate (2,2...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959859/ https://www.ncbi.nlm.nih.gov/pubmed/21581159 http://dx.doi.org/10.1107/S1600536808036866 |
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author | An, Zhe Niu, Xian-Chun |
author_facet | An, Zhe Niu, Xian-Chun |
author_sort | An, Zhe |
collection | PubMed |
description | In the title compound, [Ni(C(14)H(8)O(4))(C(10)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is coordinated in a slightly distorted octahedral geometry by two water molecules, two N atoms from a 2,2′-bipyridine ligand and two O atoms from the carboxylate groups of two 2,2′-biphenyldicarboxylate (2,2′-dpa) ligands. The 2,2′-dpa ligand acts as a bridge between neighbouring Ni(II) atoms, forming one-dimensional coordination polymers along [100]. The coordinated water molecules form hydrogen bonds to the carboxylate O atoms of 2,2′-dpa within the same coordination polymer, and one O—H⋯π interaction is also formed to 2,2′-dpa. |
format | Text |
id | pubmed-2959859 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598592010-12-30 catena-Poly[[diaqua(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2) O:O′] An, Zhe Niu, Xian-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(14)H(8)O(4))(C(10)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is coordinated in a slightly distorted octahedral geometry by two water molecules, two N atoms from a 2,2′-bipyridine ligand and two O atoms from the carboxylate groups of two 2,2′-biphenyldicarboxylate (2,2′-dpa) ligands. The 2,2′-dpa ligand acts as a bridge between neighbouring Ni(II) atoms, forming one-dimensional coordination polymers along [100]. The coordinated water molecules form hydrogen bonds to the carboxylate O atoms of 2,2′-dpa within the same coordination polymer, and one O—H⋯π interaction is also formed to 2,2′-dpa. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959859/ /pubmed/21581159 http://dx.doi.org/10.1107/S1600536808036866 Text en © An and Niu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers An, Zhe Niu, Xian-Chun catena-Poly[[diaqua(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2) O:O′] |
title |
catena-Poly[[diaqua(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2)
O:O′] |
title_full |
catena-Poly[[diaqua(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2)
O:O′] |
title_fullStr |
catena-Poly[[diaqua(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2)
O:O′] |
title_full_unstemmed |
catena-Poly[[diaqua(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2)
O:O′] |
title_short |
catena-Poly[[diaqua(2,2′-bipyridine-κ(2)
N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ(2)
O:O′] |
title_sort | catena-poly[[diaqua(2,2′-bipyridine-κ(2)
n,n′)nickel(ii)]-μ-biphenyl-2,2′-dicarboxylato-κ(2)
o:o′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959859/ https://www.ncbi.nlm.nih.gov/pubmed/21581159 http://dx.doi.org/10.1107/S1600536808036866 |
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