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catena-Poly[[diaqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) O:O′]

In the title compound, [Ni(C(14)H(8)O(4))(C(10)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is coordinated in a slightly distorted octa­hedral geometry by two water mol­ecules, two N atoms from a 2,2′-bipyridine ligand and two O atoms from the carboxyl­ate groups of two 2,2′-biphenyl­dicarboxyl­ate (2,2...

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Detalles Bibliográficos
Autores principales: An, Zhe, Niu, Xian-Chun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959859/
https://www.ncbi.nlm.nih.gov/pubmed/21581159
http://dx.doi.org/10.1107/S1600536808036866
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author An, Zhe
Niu, Xian-Chun
author_facet An, Zhe
Niu, Xian-Chun
author_sort An, Zhe
collection PubMed
description In the title compound, [Ni(C(14)H(8)O(4))(C(10)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is coordinated in a slightly distorted octa­hedral geometry by two water mol­ecules, two N atoms from a 2,2′-bipyridine ligand and two O atoms from the carboxyl­ate groups of two 2,2′-biphenyl­dicarboxyl­ate (2,2′-dpa) ligands. The 2,2′-dpa ligand acts as a bridge between neighbouring Ni(II) atoms, forming one-dimensional coordination polymers along [100]. The coordinated water mol­ecules form hydrogen bonds to the carboxyl­ate O atoms of 2,2′-dpa within the same coordination polymer, and one O—H⋯π inter­action is also formed to 2,2′-dpa.
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spelling pubmed-29598592010-12-30 catena-Poly[[diaqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) O:O′] An, Zhe Niu, Xian-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(14)H(8)O(4))(C(10)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is coordinated in a slightly distorted octa­hedral geometry by two water mol­ecules, two N atoms from a 2,2′-bipyridine ligand and two O atoms from the carboxyl­ate groups of two 2,2′-biphenyl­dicarboxyl­ate (2,2′-dpa) ligands. The 2,2′-dpa ligand acts as a bridge between neighbouring Ni(II) atoms, forming one-dimensional coordination polymers along [100]. The coordinated water mol­ecules form hydrogen bonds to the carboxyl­ate O atoms of 2,2′-dpa within the same coordination polymer, and one O—H⋯π inter­action is also formed to 2,2′-dpa. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959859/ /pubmed/21581159 http://dx.doi.org/10.1107/S1600536808036866 Text en © An and Niu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
An, Zhe
Niu, Xian-Chun
catena-Poly[[diaqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) O:O′]
title catena-Poly[[diaqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) O:O′]
title_full catena-Poly[[diaqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) O:O′]
title_fullStr catena-Poly[[diaqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[diaqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) O:O′]
title_short catena-Poly[[diaqua­(2,2′-bipyridine-κ(2) N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) O:O′]
title_sort catena-poly[[diaqua­(2,2′-bipyridine-κ(2) n,n′)nickel(ii)]-μ-biphenyl-2,2′-dicarboxyl­ato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959859/
https://www.ncbi.nlm.nih.gov/pubmed/21581159
http://dx.doi.org/10.1107/S1600536808036866
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AT niuxianchun catenapolydiaqua22bipyridinek2nnnickeliimbiphenyl22dicarboxylatok2oo