2,2′-(Butane-1,4-di­yl)diisoquinolinium tetra­chloridozincate(II)

The crystal of the title compound, (C(22)H(22)N(2))[ZnCl(4)], consists of 2,2′-(butane-1,4-di­yl)diisoquinolinium organic cations and [ZnCl(4)](2−) complex anions. The cation is located across a twofold axis and the Zn(II) atom of the anion is located on the other twofold axis. The centroid–centroid...

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Detalles Bibliográficos
Autores principales: Fan, Zhi-Fang, Xiao, Xin, Zhang, Yun-Qian, Xue, Sai-Feng, Tao, Zhu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959863/
https://www.ncbi.nlm.nih.gov/pubmed/21581211
http://dx.doi.org/10.1107/S1600536808038932
Descripción
Sumario:The crystal of the title compound, (C(22)H(22)N(2))[ZnCl(4)], consists of 2,2′-(butane-1,4-di­yl)diisoquinolinium organic cations and [ZnCl(4)](2−) complex anions. The cation is located across a twofold axis and the Zn(II) atom of the anion is located on the other twofold axis. The centroid–centroid distance between parallel pyridine rings of neighboring mol­ecules is 3.699 (3) Å, but the face-to-face separation of 3.601 (3) Å suggests there is no significant π–π stacking in the crystal structure.

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