Cargando…
2,2′-(Butane-1,4-diyl)diisoquinolinium tetrachloridozincate(II)
The crystal of the title compound, (C(22)H(22)N(2))[ZnCl(4)], consists of 2,2′-(butane-1,4-diyl)diisoquinolinium organic cations and [ZnCl(4)](2−) complex anions. The cation is located across a twofold axis and the Zn(II) atom of the anion is located on the other twofold axis. The centroid–centroid...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959863/ https://www.ncbi.nlm.nih.gov/pubmed/21581211 http://dx.doi.org/10.1107/S1600536808038932 |
_version_ | 1782188601704972288 |
---|---|
author | Fan, Zhi-Fang Xiao, Xin Zhang, Yun-Qian Xue, Sai-Feng Tao, Zhu |
author_facet | Fan, Zhi-Fang Xiao, Xin Zhang, Yun-Qian Xue, Sai-Feng Tao, Zhu |
author_sort | Fan, Zhi-Fang |
collection | PubMed |
description | The crystal of the title compound, (C(22)H(22)N(2))[ZnCl(4)], consists of 2,2′-(butane-1,4-diyl)diisoquinolinium organic cations and [ZnCl(4)](2−) complex anions. The cation is located across a twofold axis and the Zn(II) atom of the anion is located on the other twofold axis. The centroid–centroid distance between parallel pyridine rings of neighboring molecules is 3.699 (3) Å, but the face-to-face separation of 3.601 (3) Å suggests there is no significant π–π stacking in the crystal structure. |
format | Text |
id | pubmed-2959863 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598632010-12-30 2,2′-(Butane-1,4-diyl)diisoquinolinium tetrachloridozincate(II) Fan, Zhi-Fang Xiao, Xin Zhang, Yun-Qian Xue, Sai-Feng Tao, Zhu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal of the title compound, (C(22)H(22)N(2))[ZnCl(4)], consists of 2,2′-(butane-1,4-diyl)diisoquinolinium organic cations and [ZnCl(4)](2−) complex anions. The cation is located across a twofold axis and the Zn(II) atom of the anion is located on the other twofold axis. The centroid–centroid distance between parallel pyridine rings of neighboring molecules is 3.699 (3) Å, but the face-to-face separation of 3.601 (3) Å suggests there is no significant π–π stacking in the crystal structure. International Union of Crystallography 2008-11-26 /pmc/articles/PMC2959863/ /pubmed/21581211 http://dx.doi.org/10.1107/S1600536808038932 Text en © Fan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Zhi-Fang Xiao, Xin Zhang, Yun-Qian Xue, Sai-Feng Tao, Zhu 2,2′-(Butane-1,4-diyl)diisoquinolinium tetrachloridozincate(II) |
title | 2,2′-(Butane-1,4-diyl)diisoquinolinium tetrachloridozincate(II) |
title_full | 2,2′-(Butane-1,4-diyl)diisoquinolinium tetrachloridozincate(II) |
title_fullStr | 2,2′-(Butane-1,4-diyl)diisoquinolinium tetrachloridozincate(II) |
title_full_unstemmed | 2,2′-(Butane-1,4-diyl)diisoquinolinium tetrachloridozincate(II) |
title_short | 2,2′-(Butane-1,4-diyl)diisoquinolinium tetrachloridozincate(II) |
title_sort | 2,2′-(butane-1,4-diyl)diisoquinolinium tetrachloridozincate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959863/ https://www.ncbi.nlm.nih.gov/pubmed/21581211 http://dx.doi.org/10.1107/S1600536808038932 |
work_keys_str_mv | AT fanzhifang 22butane14diyldiisoquinoliniumtetrachloridozincateii AT xiaoxin 22butane14diyldiisoquinoliniumtetrachloridozincateii AT zhangyunqian 22butane14diyldiisoquinoliniumtetrachloridozincateii AT xuesaifeng 22butane14diyldiisoquinoliniumtetrachloridozincateii AT taozhu 22butane14diyldiisoquinoliniumtetrachloridozincateii |