Cargando…
Poly[[triaqua[μ(4)-N-(4-carboxylatophenyl)iminodiacetato]sodium(I)zinc(II)] dihydrate]
In the title coordination polymer, {[NaZn(C(11)H(8)NO(6))(H(2)O)(3)]·2H(2)O}(n), the Zn atom is coordinated in a distorted tetrahedral environment by three carboxylate O atoms from two (4-carboxylatophenylimino)diacetate ligands and one water molecule; the Na atom is in an distorted octahedral...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959866/ https://www.ncbi.nlm.nih.gov/pubmed/21581140 http://dx.doi.org/10.1107/S1600536808036441 |
_version_ | 1782188602424295424 |
---|---|
author | Ma, Dong-Sheng |
author_facet | Ma, Dong-Sheng |
author_sort | Ma, Dong-Sheng |
collection | PubMed |
description | In the title coordination polymer, {[NaZn(C(11)H(8)NO(6))(H(2)O)(3)]·2H(2)O}(n), the Zn atom is coordinated in a distorted tetrahedral environment by three carboxylate O atoms from two (4-carboxylatophenylimino)diacetate ligands and one water molecule; the Na atom is in an distorted octahedral coordination environment formed by four carboxylate O atoms from three (4-carboxylatophenylimino)diacetate ligands and two water molecules. The Zn atoms and Na atoms are linked by (4-carboxylatophenylimino)diacetate ligands into a three-dimensional framework; the uncoordinated water molecules fill the voids of the skeleton and stabilize it by O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2959866 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598662010-12-30 Poly[[triaqua[μ(4)-N-(4-carboxylatophenyl)iminodiacetato]sodium(I)zinc(II)] dihydrate] Ma, Dong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[NaZn(C(11)H(8)NO(6))(H(2)O)(3)]·2H(2)O}(n), the Zn atom is coordinated in a distorted tetrahedral environment by three carboxylate O atoms from two (4-carboxylatophenylimino)diacetate ligands and one water molecule; the Na atom is in an distorted octahedral coordination environment formed by four carboxylate O atoms from three (4-carboxylatophenylimino)diacetate ligands and two water molecules. The Zn atoms and Na atoms are linked by (4-carboxylatophenylimino)diacetate ligands into a three-dimensional framework; the uncoordinated water molecules fill the voids of the skeleton and stabilize it by O—H⋯O hydrogen bonds. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959866/ /pubmed/21581140 http://dx.doi.org/10.1107/S1600536808036441 Text en © Dong-Sheng Ma 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Dong-Sheng Poly[[triaqua[μ(4)-N-(4-carboxylatophenyl)iminodiacetato]sodium(I)zinc(II)] dihydrate] |
title | Poly[[triaqua[μ(4)-N-(4-carboxylatophenyl)iminodiacetato]sodium(I)zinc(II)] dihydrate] |
title_full | Poly[[triaqua[μ(4)-N-(4-carboxylatophenyl)iminodiacetato]sodium(I)zinc(II)] dihydrate] |
title_fullStr | Poly[[triaqua[μ(4)-N-(4-carboxylatophenyl)iminodiacetato]sodium(I)zinc(II)] dihydrate] |
title_full_unstemmed | Poly[[triaqua[μ(4)-N-(4-carboxylatophenyl)iminodiacetato]sodium(I)zinc(II)] dihydrate] |
title_short | Poly[[triaqua[μ(4)-N-(4-carboxylatophenyl)iminodiacetato]sodium(I)zinc(II)] dihydrate] |
title_sort | poly[[triaqua[μ(4)-n-(4-carboxylatophenyl)iminodiacetato]sodium(i)zinc(ii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959866/ https://www.ncbi.nlm.nih.gov/pubmed/21581140 http://dx.doi.org/10.1107/S1600536808036441 |
work_keys_str_mv | AT madongsheng polytriaquam4n4carboxylatophenyliminodiacetatosodiumizinciidihydrate |