Diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(II) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(III)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate

The title compound, [Fe(C(10)H(20)O(5))(H(2)O)(2)][Fe(2)(C(4)N(2)S(2))(4)]·2C(10)H(20)O(5), consists of an [Fe(II)(15-crown-5)(H(2)O)(2)](2+) cation, sandwiched between and O—H⋯O hydrogen bonded by two additional 15-crown-5 ether mol­ecules and two independent [Fe(III)(mnt)(2)](−) anions, where 15-c...

Descripción completa

Detalles Bibliográficos
Autores principales: Yamaguchi, Toshiki, Masaoka, Shigeyuki, Sakai, Ken
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959872/
https://www.ncbi.nlm.nih.gov/pubmed/21581166
http://dx.doi.org/10.1107/S1600536808036805
_version_ 1782188603833581568
author Yamaguchi, Toshiki
Masaoka, Shigeyuki
Sakai, Ken
author_facet Yamaguchi, Toshiki
Masaoka, Shigeyuki
Sakai, Ken
author_sort Yamaguchi, Toshiki
collection PubMed
description The title compound, [Fe(C(10)H(20)O(5))(H(2)O)(2)][Fe(2)(C(4)N(2)S(2))(4)]·2C(10)H(20)O(5), consists of an [Fe(II)(15-crown-5)(H(2)O)(2)](2+) cation, sandwiched between and O—H⋯O hydrogen bonded by two additional 15-crown-5 ether mol­ecules and two independent [Fe(III)(mnt)(2)](−) anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta­oxacyclo­penta­decane and mnt denotes cis-1,2-dicyano-1,2-ethyl­enedithiol­ate. Each independent [Fe(III)(mnt)(2)](−) unit forms a centrosymmetric dimer supported by two inter­monomer Fe(III)—S bonds [Fe—S = 2.4715 (9) and 2.4452 (9) Å]. In the crystal structure, the dimers form one-dimensional π–π stacks along the a axis, with an inter­planar separation of 3.38 (6) Å.
format Text
id pubmed-2959872
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29598722010-12-30 Diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(II) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(III)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate Yamaguchi, Toshiki Masaoka, Shigeyuki Sakai, Ken Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(10)H(20)O(5))(H(2)O)(2)][Fe(2)(C(4)N(2)S(2))(4)]·2C(10)H(20)O(5), consists of an [Fe(II)(15-crown-5)(H(2)O)(2)](2+) cation, sandwiched between and O—H⋯O hydrogen bonded by two additional 15-crown-5 ether mol­ecules and two independent [Fe(III)(mnt)(2)](−) anions, where 15-crown-5 ether denotes 1,4,7,10,13-penta­oxacyclo­penta­decane and mnt denotes cis-1,2-dicyano-1,2-ethyl­enedithiol­ate. Each independent [Fe(III)(mnt)(2)](−) unit forms a centrosymmetric dimer supported by two inter­monomer Fe(III)—S bonds [Fe—S = 2.4715 (9) and 2.4452 (9) Å]. In the crystal structure, the dimers form one-dimensional π–π stacks along the a axis, with an inter­planar separation of 3.38 (6) Å. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959872/ /pubmed/21581166 http://dx.doi.org/10.1107/S1600536808036805 Text en © Yamaguchi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yamaguchi, Toshiki
Masaoka, Shigeyuki
Sakai, Ken
Diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(II) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(III)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate
title Diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(II) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(III)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate
title_full Diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(II) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(III)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate
title_fullStr Diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(II) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(III)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate
title_full_unstemmed Diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(II) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(III)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate
title_short Diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(II) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(III)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate
title_sort diaqua­(1,4,7,10,13-penta­oxacyclo­penta­deca­ne)iron(ii) bis­(μ-cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)bis­[(cis-1,2-dicyano-1,2-ethyl­enedithiol­ato)ferrate(iii)] 1,4,7,10,13-penta­oxacyclo­penta­decane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959872/
https://www.ncbi.nlm.nih.gov/pubmed/21581166
http://dx.doi.org/10.1107/S1600536808036805
work_keys_str_mv AT yamaguchitoshiki diaqua1471013pentaoxacyclopentadecaneironiibismcis12dicyano12ethylenedithiolatobiscis12dicyano12ethylenedithiolatoferrateiii1471013pentaoxacyclopentadecanedisolvate
AT masaokashigeyuki diaqua1471013pentaoxacyclopentadecaneironiibismcis12dicyano12ethylenedithiolatobiscis12dicyano12ethylenedithiolatoferrateiii1471013pentaoxacyclopentadecanedisolvate
AT sakaiken diaqua1471013pentaoxacyclopentadecaneironiibismcis12dicyano12ethylenedithiolatobiscis12dicyano12ethylenedithiolatoferrateiii1471013pentaoxacyclopentadecanedisolvate

Ejemplares similares