2-Amino-1H-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide

In the title compound, C(7)H(8)N(3) (+)·C(10)H(6)F(3)O(2) (−), 1H-benzoimidazol-2-amine system adopts a planar conformation with an r.m.s. deviation of 0.0174 Å. The cation and anion in the asymmetric unit are linked by N—H⋯O hydrogen bonds. There are also additional inter­molecular N—H⋯O hydrogen b...

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Detalles Bibliográficos
Autores principales: Li, Gong-Chun, Yang, Feng-Ling, Yao, Chang-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959878/
https://www.ncbi.nlm.nih.gov/pubmed/21581428
http://dx.doi.org/10.1107/S1600536808037483
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author Li, Gong-Chun
Yang, Feng-Ling
Yao, Chang-Sheng
author_facet Li, Gong-Chun
Yang, Feng-Ling
Yao, Chang-Sheng
author_sort Li, Gong-Chun
collection PubMed
description In the title compound, C(7)H(8)N(3) (+)·C(10)H(6)F(3)O(2) (−), 1H-benzoimidazol-2-amine system adopts a planar conformation with an r.m.s. deviation of 0.0174 Å. The cation and anion in the asymmetric unit are linked by N—H⋯O hydrogen bonds. There are also additional inter­molecular N—H⋯O hydrogen bonds and π–π stacking inter­actions between the phenyl rings of neighbouring anions with centroid–centroid distances of 4.0976 (13) Å.
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spelling pubmed-29598782010-12-30 2-Amino-1H-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide Li, Gong-Chun Yang, Feng-Ling Yao, Chang-Sheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(8)N(3) (+)·C(10)H(6)F(3)O(2) (−), 1H-benzoimidazol-2-amine system adopts a planar conformation with an r.m.s. deviation of 0.0174 Å. The cation and anion in the asymmetric unit are linked by N—H⋯O hydrogen bonds. There are also additional inter­molecular N—H⋯O hydrogen bonds and π–π stacking inter­actions between the phenyl rings of neighbouring anions with centroid–centroid distances of 4.0976 (13) Å. International Union of Crystallography 2008-11-26 /pmc/articles/PMC2959878/ /pubmed/21581428 http://dx.doi.org/10.1107/S1600536808037483 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Gong-Chun
Yang, Feng-Ling
Yao, Chang-Sheng
2-Amino-1H-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide
title 2-Amino-1H-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide
title_full 2-Amino-1H-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide
title_fullStr 2-Amino-1H-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide
title_full_unstemmed 2-Amino-1H-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide
title_short 2-Amino-1H-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide
title_sort 2-amino-1h-benzoimidazol-3-ium 4,4,4-trifluoro-1,3-dioxo-1-phenyl­butan-2-ide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959878/
https://www.ncbi.nlm.nih.gov/pubmed/21581428
http://dx.doi.org/10.1107/S1600536808037483
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AT yangfengling 2amino1hbenzoimidazol3ium444trifluoro13dioxo1phenylbutan2ide
AT yaochangsheng 2amino1hbenzoimidazol3ium444trifluoro13dioxo1phenylbutan2ide

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