Cargando…

N,N′-Bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine

The mol­ecule of the title Schiff base compound, C(19)H(18)Cl(4)N(2), has crystallographic twofold rotation symmetry, with one C atom lying on the rotation axis. The dihedral angle between the two symmetry-related benzene rings is 84.70 (2)°. The plane of the –C=N—C– group is twisted away from the b...

Descripción completa

Detalles Bibliográficos
Autores principales: Kia, Reza, Fun, Hoong-Kun, Kargar, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959888/
https://www.ncbi.nlm.nih.gov/pubmed/21581264
http://dx.doi.org/10.1107/S1600536808035745
_version_ 1782188607661932544
author Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_facet Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_sort Kia, Reza
collection PubMed
description The mol­ecule of the title Schiff base compound, C(19)H(18)Cl(4)N(2), has crystallographic twofold rotation symmetry, with one C atom lying on the rotation axis. The dihedral angle between the two symmetry-related benzene rings is 84.70 (2)°. The plane of the –C=N—C– group is twisted away from the benzene ring by 7.5 (1)°. In the crystal structure, weak inter­molecular Cl⋯Cl [3.4851 (3) Å] contacts link neighbouring mol­ecules into a two-dimensional network parallel to the bc plane.
format Text
id pubmed-2959888
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29598882010-12-30 N,N′-Bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title Schiff base compound, C(19)H(18)Cl(4)N(2), has crystallographic twofold rotation symmetry, with one C atom lying on the rotation axis. The dihedral angle between the two symmetry-related benzene rings is 84.70 (2)°. The plane of the –C=N—C– group is twisted away from the benzene ring by 7.5 (1)°. In the crystal structure, weak inter­molecular Cl⋯Cl [3.4851 (3) Å] contacts link neighbouring mol­ecules into a two-dimensional network parallel to the bc plane. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959888/ /pubmed/21581264 http://dx.doi.org/10.1107/S1600536808035745 Text en © Kia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
N,N′-Bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title N,N′-Bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_full N,N′-Bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_fullStr N,N′-Bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_full_unstemmed N,N′-Bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_short N,N′-Bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_sort n,n′-bis-(2,4-dichloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959888/
https://www.ncbi.nlm.nih.gov/pubmed/21581264
http://dx.doi.org/10.1107/S1600536808035745
work_keys_str_mv AT kiareza nnbis24dichlorobenzylidene22dimethylpropane13diamine
AT funhoongkun nnbis24dichlorobenzylidene22dimethylpropane13diamine
AT kargarhadi nnbis24dichlorobenzylidene22dimethylpropane13diamine