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N,N′-Bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine
The molecule of the title Schiff base compound, C(19)H(18)Cl(4)N(2), has crystallographic twofold rotation symmetry, with one C atom lying on the rotation axis. The dihedral angle between the two symmetry-related benzene rings is 84.70 (2)°. The plane of the –C=N—C– group is twisted away from the b...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959888/ https://www.ncbi.nlm.nih.gov/pubmed/21581264 http://dx.doi.org/10.1107/S1600536808035745 |
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author | Kia, Reza Fun, Hoong-Kun Kargar, Hadi |
author_facet | Kia, Reza Fun, Hoong-Kun Kargar, Hadi |
author_sort | Kia, Reza |
collection | PubMed |
description | The molecule of the title Schiff base compound, C(19)H(18)Cl(4)N(2), has crystallographic twofold rotation symmetry, with one C atom lying on the rotation axis. The dihedral angle between the two symmetry-related benzene rings is 84.70 (2)°. The plane of the –C=N—C– group is twisted away from the benzene ring by 7.5 (1)°. In the crystal structure, weak intermolecular Cl⋯Cl [3.4851 (3) Å] contacts link neighbouring molecules into a two-dimensional network parallel to the bc plane. |
format | Text |
id | pubmed-2959888 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29598882010-12-30 N,N′-Bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title Schiff base compound, C(19)H(18)Cl(4)N(2), has crystallographic twofold rotation symmetry, with one C atom lying on the rotation axis. The dihedral angle between the two symmetry-related benzene rings is 84.70 (2)°. The plane of the –C=N—C– group is twisted away from the benzene ring by 7.5 (1)°. In the crystal structure, weak intermolecular Cl⋯Cl [3.4851 (3) Å] contacts link neighbouring molecules into a two-dimensional network parallel to the bc plane. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959888/ /pubmed/21581264 http://dx.doi.org/10.1107/S1600536808035745 Text en © Kia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kia, Reza Fun, Hoong-Kun Kargar, Hadi N,N′-Bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine |
title |
N,N′-Bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine |
title_full |
N,N′-Bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine |
title_fullStr |
N,N′-Bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine |
title_full_unstemmed |
N,N′-Bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine |
title_short |
N,N′-Bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine |
title_sort | n,n′-bis-(2,4-dichlorobenzylidene)-2,2-dimethylpropane-1,3-diamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959888/ https://www.ncbi.nlm.nih.gov/pubmed/21581264 http://dx.doi.org/10.1107/S1600536808035745 |
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