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[3-(4-Chlorophenyl)-5-hydroxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyridyl)methanone
In the title compound, C(21)H(16)ClN(3)O(2), the dihedral angles formed by the pyrazole ring with the pyridyl, phenylene and phenyl rings are 6.80 (5), 9.23 (5) and 74.96 (5)°, respectively. The phenyl and phenylene rings are inclined at 80.14 (2)°. Intramolecular O—H⋯O and C—H⋯N hydrogen bonds g...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959893/ https://www.ncbi.nlm.nih.gov/pubmed/21581336 http://dx.doi.org/10.1107/S1600536808037161 |
Sumario: | In the title compound, C(21)H(16)ClN(3)O(2), the dihedral angles formed by the pyrazole ring with the pyridyl, phenylene and phenyl rings are 6.80 (5), 9.23 (5) and 74.96 (5)°, respectively. The phenyl and phenylene rings are inclined at 80.14 (2)°. Intramolecular O—H⋯O and C—H⋯N hydrogen bonds generate S(6) ring motifs. The crystal packing is strengthened by short intermolecular O—H⋯N, C—H⋯O hydrogen bonds and π–π stacking interactions with centroid–centroid distances of 3.6247 (5)–3.7205 (5) Å, together with intermolecular short O⋯N contacts [2.7682 (11) Å]. Molecules are linked into infinite chains along [100]. |
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