[3-(4-Chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyrid­yl)methanone

In the title compound, C(21)H(16)ClN(3)O(2), the dihedral angles formed by the pyrazole ring with the pyridyl, phenyl­ene and phenyl rings are 6.80 (5), 9.23 (5) and 74.96 (5)°, respectively. The phenyl and phenyl­ene rings are inclined at 80.14 (2)°. Intra­molecular O—H⋯O and C—H⋯N hydrogen bonds g...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Rao, Jyothi N., Kalluraya, B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959893/
https://www.ncbi.nlm.nih.gov/pubmed/21581336
http://dx.doi.org/10.1107/S1600536808037161
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author Fun, Hoong-Kun
Jebas, Samuel Robinson
Rao, Jyothi N.
Kalluraya, B.
author_facet Fun, Hoong-Kun
Jebas, Samuel Robinson
Rao, Jyothi N.
Kalluraya, B.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(21)H(16)ClN(3)O(2), the dihedral angles formed by the pyrazole ring with the pyridyl, phenyl­ene and phenyl rings are 6.80 (5), 9.23 (5) and 74.96 (5)°, respectively. The phenyl and phenyl­ene rings are inclined at 80.14 (2)°. Intra­molecular O—H⋯O and C—H⋯N hydrogen bonds generate S(6) ring motifs. The crystal packing is strengthened by short inter­molecular O—H⋯N, C—H⋯O hydrogen bonds and π–π stacking inter­actions with centroid–centroid distances of 3.6247 (5)–3.7205 (5) Å, together with inter­molecular short O⋯N contacts [2.7682 (11) Å]. Mol­ecules are linked into infinite chains along [100].
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spelling pubmed-29598932010-12-30 [3-(4-Chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyrid­yl)methanone Fun, Hoong-Kun Jebas, Samuel Robinson Rao, Jyothi N. Kalluraya, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(16)ClN(3)O(2), the dihedral angles formed by the pyrazole ring with the pyridyl, phenyl­ene and phenyl rings are 6.80 (5), 9.23 (5) and 74.96 (5)°, respectively. The phenyl and phenyl­ene rings are inclined at 80.14 (2)°. Intra­molecular O—H⋯O and C—H⋯N hydrogen bonds generate S(6) ring motifs. The crystal packing is strengthened by short inter­molecular O—H⋯N, C—H⋯O hydrogen bonds and π–π stacking inter­actions with centroid–centroid distances of 3.6247 (5)–3.7205 (5) Å, together with inter­molecular short O⋯N contacts [2.7682 (11) Å]. Mol­ecules are linked into infinite chains along [100]. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959893/ /pubmed/21581336 http://dx.doi.org/10.1107/S1600536808037161 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Jebas, Samuel Robinson
Rao, Jyothi N.
Kalluraya, B.
[3-(4-Chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyrid­yl)methanone
title [3-(4-Chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyrid­yl)methanone
title_full [3-(4-Chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyrid­yl)methanone
title_fullStr [3-(4-Chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyrid­yl)methanone
title_full_unstemmed [3-(4-Chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyrid­yl)methanone
title_short [3-(4-Chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1H-pyrazol-1-yl](3-pyrid­yl)methanone
title_sort [3-(4-chloro­phen­yl)-5-hydr­oxy-5-phenyl-4,5-dihydro-1h-pyrazol-1-yl](3-pyrid­yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959893/
https://www.ncbi.nlm.nih.gov/pubmed/21581336
http://dx.doi.org/10.1107/S1600536808037161
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AT raojyothin 34chlorophenyl5hydroxy5phenyl45dihydro1hpyrazol1yl3pyridylmethanone
AT kallurayab 34chlorophenyl5hydroxy5phenyl45dihydro1hpyrazol1yl3pyridylmethanone

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