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Hexakis(μ(2)-2-aminoethanethiolato)triiron(III) tris(perchlorate)
In the title salt, [Fe(3)(C(2)H(6)NS)(6)](ClO(4))(3), the trinuclear cation lies on a special position of [Image: see text] site symmetry; the central Fe atom is coordinated by six thiolate groups from the two flanking fac-(S)-[Fe(C(2)H(6)NS)(3)] units. In the flanking units, the three C(2)H(6)NS g...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959897/ https://www.ncbi.nlm.nih.gov/pubmed/21581137 http://dx.doi.org/10.1107/S1600536808036167 |
Sumario: | In the title salt, [Fe(3)(C(2)H(6)NS)(6)](ClO(4))(3), the trinuclear cation lies on a special position of [Image: see text] site symmetry; the central Fe atom is coordinated by six thiolate groups from the two flanking fac-(S)-[Fe(C(2)H(6)NS)(3)] units. In the flanking units, the three C(2)H(6)NS groups each chelate to the metal atom. The cations interact with the perchlorate anions through weak N—H⋯O hydrogen bonds resulting in a three-dimensional network. In the asymmetric unit two cations are present, one of which is disordered over two positions with occupancies of 0.75 and 0.25. |
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