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Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate)

In the title salt, [Fe(3)(C(2)H(6)NS)(6)](ClO(4))(3), the trinuclear cation lies on a special position of [Image: see text] site symmetry; the central Fe atom is coordinated by six thiol­ate groups from the two flanking fac-(S)-[Fe(C(2)H(6)NS)(3)] units. In the flanking units, the three C(2)H(6)NS g...

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Detalles Bibliográficos
Autores principales: Igashira-Kamiyama, Asako, Konno, Takumi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959897/
https://www.ncbi.nlm.nih.gov/pubmed/21581137
http://dx.doi.org/10.1107/S1600536808036167
Descripción
Sumario:In the title salt, [Fe(3)(C(2)H(6)NS)(6)](ClO(4))(3), the trinuclear cation lies on a special position of [Image: see text] site symmetry; the central Fe atom is coordinated by six thiol­ate groups from the two flanking fac-(S)-[Fe(C(2)H(6)NS)(3)] units. In the flanking units, the three C(2)H(6)NS groups each chelate to the metal atom. The cations inter­act with the perchlorate anions through weak N—H⋯O hydrogen bonds resulting in a three-dimensional network. In the asymmetric unit two cations are present, one of which is disordered over two positions with occupancies of 0.75 and 0.25.