Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate)

In the title salt, [Fe(3)(C(2)H(6)NS)(6)](ClO(4))(3), the trinuclear cation lies on a special position of [Image: see text] site symmetry; the central Fe atom is coordinated by six thiol­ate groups from the two flanking fac-(S)-[Fe(C(2)H(6)NS)(3)] units. In the flanking units, the three C(2)H(6)NS g...

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Detalles Bibliográficos
Autores principales: Igashira-Kamiyama, Asako, Konno, Takumi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959897/
https://www.ncbi.nlm.nih.gov/pubmed/21581137
http://dx.doi.org/10.1107/S1600536808036167
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author Igashira-Kamiyama, Asako
Konno, Takumi
author_facet Igashira-Kamiyama, Asako
Konno, Takumi
author_sort Igashira-Kamiyama, Asako
collection PubMed
description In the title salt, [Fe(3)(C(2)H(6)NS)(6)](ClO(4))(3), the trinuclear cation lies on a special position of [Image: see text] site symmetry; the central Fe atom is coordinated by six thiol­ate groups from the two flanking fac-(S)-[Fe(C(2)H(6)NS)(3)] units. In the flanking units, the three C(2)H(6)NS groups each chelate to the metal atom. The cations inter­act with the perchlorate anions through weak N—H⋯O hydrogen bonds resulting in a three-dimensional network. In the asymmetric unit two cations are present, one of which is disordered over two positions with occupancies of 0.75 and 0.25.
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spelling pubmed-29598972010-12-30 Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate) Igashira-Kamiyama, Asako Konno, Takumi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Fe(3)(C(2)H(6)NS)(6)](ClO(4))(3), the trinuclear cation lies on a special position of [Image: see text] site symmetry; the central Fe atom is coordinated by six thiol­ate groups from the two flanking fac-(S)-[Fe(C(2)H(6)NS)(3)] units. In the flanking units, the three C(2)H(6)NS groups each chelate to the metal atom. The cations inter­act with the perchlorate anions through weak N—H⋯O hydrogen bonds resulting in a three-dimensional network. In the asymmetric unit two cations are present, one of which is disordered over two positions with occupancies of 0.75 and 0.25. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959897/ /pubmed/21581137 http://dx.doi.org/10.1107/S1600536808036167 Text en © Igashira-Kamiyama and Konno 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Igashira-Kamiyama, Asako
Konno, Takumi
Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate)
title Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate)
title_full Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate)
title_fullStr Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate)
title_full_unstemmed Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate)
title_short Hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(III) tris(perchlorate)
title_sort hexakis(μ(2)-2-amino­ethanethiol­ato)­triiron(iii) tris(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959897/
https://www.ncbi.nlm.nih.gov/pubmed/21581137
http://dx.doi.org/10.1107/S1600536808036167
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AT konnotakumi hexakism22aminoethanethiolatotriironiiitrisperchlorate

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