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Triazido­[tris­(2-pyridyl-κN)methyl­amine]cobalt(III)

The title compound, [Co(N(3))(3)(C(16)H(14)N(4))], was synthesized by hydro­thermal reaction of [Co(NH(3))(6)](NO(3))(3), NaN(3) and tris­(2-pyrid­yl)methyl­amine. The structure contains two independent complexes in the asymmetric unit, with closely comparable geometry. The Co(III) atoms are hexa­co...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Liu, Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959905/
https://www.ncbi.nlm.nih.gov/pubmed/21581120
http://dx.doi.org/10.1107/S1600536808035162
Descripción
Sumario:The title compound, [Co(N(3))(3)(C(16)H(14)N(4))], was synthesized by hydro­thermal reaction of [Co(NH(3))(6)](NO(3))(3), NaN(3) and tris­(2-pyrid­yl)methyl­amine. The structure contains two independent complexes in the asymmetric unit, with closely comparable geometry. The Co(III) atoms are hexa­coordinated by three N atoms from the tridentate tris­(2-pyrid­yl)methyl­amine ligands and three azide ions in a fac arrangement. N—H⋯N hydrogen bonds are formed between the amino group and the uncoordinated terminal N atoms of the azide ligands.