{6,6′-Dieth­oxy-2,2′-[ethyl­enebis(nitrilo­methyl­idyne)]diphenolato}nickel(II) monohydrate

In the title compound, [Ni(C(20)H(22)N(2)O(4))]·H(2)O, the Ni(II) ion and the water mol­ecule are located on a twofold rotation axis. The Ni ion is coordinated by two N [Ni—N = 1.8462 (18) Å] and two O [Ni—O = 1.8645 (14) Å] atoms in a distorted square-planar geometry. The water mol­ecule and the Ni...

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Detalles Bibliográficos
Autor principal: Xie, Hai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959910/
https://www.ncbi.nlm.nih.gov/pubmed/21581227
http://dx.doi.org/10.1107/S1600536808039822
Descripción
Sumario:In the title compound, [Ni(C(20)H(22)N(2)O(4))]·H(2)O, the Ni(II) ion and the water mol­ecule are located on a twofold rotation axis. The Ni ion is coordinated by two N [Ni—N = 1.8462 (18) Å] and two O [Ni—O = 1.8645 (14) Å] atoms in a distorted square-planar geometry. The water mol­ecule and the Ni complex mol­ecule are paired via O—H⋯O hydrogen bonds.

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