Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra­hydrate]

In the title complex, {[Cu(2)Mo(CN)(8)(C(12)H(30)N(6)O(2))(2)]·4H(2)O}(n), the polyhedron around Mo has site symmetry [Image: see text] with a distorted square-antiprismatic shape, while the Cu atom (2 symmetry) is in a distorted axially elongated octa­hedral coordination environment. The uncoordina...

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Detalles Bibliográficos
Autores principales: Zhou, Hu, Chen, Ying-Ying, Liu, Wen-Yan, Yuan, Ai-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959912/
https://www.ncbi.nlm.nih.gov/pubmed/21581144
http://dx.doi.org/10.1107/S1600536808036131
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author Zhou, Hu
Chen, Ying-Ying
Liu, Wen-Yan
Yuan, Ai-Hua
author_facet Zhou, Hu
Chen, Ying-Ying
Liu, Wen-Yan
Yuan, Ai-Hua
author_sort Zhou, Hu
collection PubMed
description In the title complex, {[Cu(2)Mo(CN)(8)(C(12)H(30)N(6)O(2))(2)]·4H(2)O}(n), the polyhedron around Mo has site symmetry [Image: see text] with a distorted square-antiprismatic shape, while the Cu atom (2 symmetry) is in a distorted axially elongated octa­hedral coordination environment. The uncoordinated water molecule is disordered over three sites with occupancies of 0.445 (7), 0.340 (7) and 0.215 (7). Mo and Cu atoms acting as basic components are connected by an Mo—CN—Cu—NC—Mo— linkage to form a distorted diamond-like network. Additional hydrogen bonding between the N—H groups and the water molecules stabilizes this arrangement.
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spelling pubmed-29599122010-12-30 Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra­hydrate] Zhou, Hu Chen, Ying-Ying Liu, Wen-Yan Yuan, Ai-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Cu(2)Mo(CN)(8)(C(12)H(30)N(6)O(2))(2)]·4H(2)O}(n), the polyhedron around Mo has site symmetry [Image: see text] with a distorted square-antiprismatic shape, while the Cu atom (2 symmetry) is in a distorted axially elongated octa­hedral coordination environment. The uncoordinated water molecule is disordered over three sites with occupancies of 0.445 (7), 0.340 (7) and 0.215 (7). Mo and Cu atoms acting as basic components are connected by an Mo—CN—Cu—NC—Mo— linkage to form a distorted diamond-like network. Additional hydrogen bonding between the N—H groups and the water molecules stabilizes this arrangement. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959912/ /pubmed/21581144 http://dx.doi.org/10.1107/S1600536808036131 Text en © Zhou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Hu
Chen, Ying-Ying
Liu, Wen-Yan
Yuan, Ai-Hua
Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra­hydrate]
title Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra­hydrate]
title_full Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra­hydrate]
title_fullStr Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra­hydrate]
title_full_unstemmed Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra­hydrate]
title_short Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra­hydrate]
title_sort poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa­azacyclo­tetra­deca­ne]tetra-μ-cyanido-tetracyanidodicopper(ii)molybdenum(iv)] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959912/
https://www.ncbi.nlm.nih.gov/pubmed/21581144
http://dx.doi.org/10.1107/S1600536808036131
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