3,4,5-Trimethoxy­benzohydrazidium chloride

The title compound, C(10)H(15)N(2)O(4) (+)·Cl(−), was obtained as an unexpected by-product during the synthesis of 1-[2-(substituted ar­yl)]-3-methyl­pyrazol-5-ones. The hydrazide group is essentially planar, with an r.s.m. deviation of 0.020 (2) Å, and is oriented at a dihedral angle of 30.52 (3)°...

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Detalles Bibliográficos
Autores principales: Saeed, Aamer, Mumtaz, Amara, Rafique, Hummera, Gotoh, Kazuma, Ishida, Hiroyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959913/
https://www.ncbi.nlm.nih.gov/pubmed/21581311
http://dx.doi.org/10.1107/S1600536808036301
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author Saeed, Aamer
Mumtaz, Amara
Rafique, Hummera
Gotoh, Kazuma
Ishida, Hiroyuki
author_facet Saeed, Aamer
Mumtaz, Amara
Rafique, Hummera
Gotoh, Kazuma
Ishida, Hiroyuki
author_sort Saeed, Aamer
collection PubMed
description The title compound, C(10)H(15)N(2)O(4) (+)·Cl(−), was obtained as an unexpected by-product during the synthesis of 1-[2-(substituted ar­yl)]-3-methyl­pyrazol-5-ones. The hydrazide group is essentially planar, with an r.s.m. deviation of 0.020 (2) Å, and is oriented at a dihedral angle of 30.52 (3)° with respect to the benzene ring. In the crystal structure, the cations and anions are linked through N—H⋯O and N—H⋯Cl hydrogen bonds, forming a mol­ecular tape running along the b axis.
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spelling pubmed-29599132010-12-30 3,4,5-Trimethoxy­benzohydrazidium chloride Saeed, Aamer Mumtaz, Amara Rafique, Hummera Gotoh, Kazuma Ishida, Hiroyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(15)N(2)O(4) (+)·Cl(−), was obtained as an unexpected by-product during the synthesis of 1-[2-(substituted ar­yl)]-3-methyl­pyrazol-5-ones. The hydrazide group is essentially planar, with an r.s.m. deviation of 0.020 (2) Å, and is oriented at a dihedral angle of 30.52 (3)° with respect to the benzene ring. In the crystal structure, the cations and anions are linked through N—H⋯O and N—H⋯Cl hydrogen bonds, forming a mol­ecular tape running along the b axis. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959913/ /pubmed/21581311 http://dx.doi.org/10.1107/S1600536808036301 Text en © Saeed et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Aamer
Mumtaz, Amara
Rafique, Hummera
Gotoh, Kazuma
Ishida, Hiroyuki
3,4,5-Trimethoxy­benzohydrazidium chloride
title 3,4,5-Trimethoxy­benzohydrazidium chloride
title_full 3,4,5-Trimethoxy­benzohydrazidium chloride
title_fullStr 3,4,5-Trimethoxy­benzohydrazidium chloride
title_full_unstemmed 3,4,5-Trimethoxy­benzohydrazidium chloride
title_short 3,4,5-Trimethoxy­benzohydrazidium chloride
title_sort 3,4,5-trimethoxy­benzohydrazidium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959913/
https://www.ncbi.nlm.nih.gov/pubmed/21581311
http://dx.doi.org/10.1107/S1600536808036301
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AT mumtazamara 345trimethoxybenzohydrazidiumchloride
AT rafiquehummera 345trimethoxybenzohydrazidiumchloride
AT gotohkazuma 345trimethoxybenzohydrazidiumchloride
AT ishidahiroyuki 345trimethoxybenzohydrazidiumchloride

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