Cargando…
Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2) N,O (1)}copper(II)
The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical intermolecular C—H⋯O hydro...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959917/ https://www.ncbi.nlm.nih.gov/pubmed/21581118 http://dx.doi.org/10.1107/S1600536808035289 |
_version_ | 1782188614584631296 |
---|---|
author | Datta, Amitabha Huang, Jui-Hsien Lee, Hon Man |
author_facet | Datta, Amitabha Huang, Jui-Hsien Lee, Hon Man |
author_sort | Datta, Amitabha |
collection | PubMed |
description | The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical intermolecular C—H⋯O hydrogen bonds involving the ether O atoms link the Schiff base molecules into a two-dimensional network parallel to (101). |
format | Text |
id | pubmed-2959917 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29599172010-12-30 Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2) N,O (1)}copper(II) Datta, Amitabha Huang, Jui-Hsien Lee, Hon Man Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical intermolecular C—H⋯O hydrogen bonds involving the ether O atoms link the Schiff base molecules into a two-dimensional network parallel to (101). International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959917/ /pubmed/21581118 http://dx.doi.org/10.1107/S1600536808035289 Text en © Datta et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Datta, Amitabha Huang, Jui-Hsien Lee, Hon Man Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2) N,O (1)}copper(II) |
title | Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_full | Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_fullStr | Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_full_unstemmed | Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_short | Bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2)
N,O
(1)}copper(II) |
title_sort | bis{2-methoxy-6-[(3-methoxypropyl)iminomethyl]phenolato-κ(2)
n,o
(1)}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959917/ https://www.ncbi.nlm.nih.gov/pubmed/21581118 http://dx.doi.org/10.1107/S1600536808035289 |
work_keys_str_mv | AT dattaamitabha bis2methoxy63methoxypropyliminomethylphenolatok2no1copperii AT huangjuihsien bis2methoxy63methoxypropyliminomethylphenolatok2no1copperii AT leehonman bis2methoxy63methoxypropyliminomethylphenolatok2no1copperii |