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Bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)

The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical inter­molecular C—H⋯O hydro...

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Detalles Bibliográficos
Autores principales: Datta, Amitabha, Huang, Jui-Hsien, Lee, Hon Man
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959917/
https://www.ncbi.nlm.nih.gov/pubmed/21581118
http://dx.doi.org/10.1107/S1600536808035289
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author Datta, Amitabha
Huang, Jui-Hsien
Lee, Hon Man
author_facet Datta, Amitabha
Huang, Jui-Hsien
Lee, Hon Man
author_sort Datta, Amitabha
collection PubMed
description The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical inter­molecular C—H⋯O hydrogen bonds involving the ether O atoms link the Schiff base mol­ecules into a two-dimensional network parallel to (101).
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spelling pubmed-29599172010-12-30 Bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II) Datta, Amitabha Huang, Jui-Hsien Lee, Hon Man Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(12)H(16)NO(3))(2)], adopts a distorted square-planar coordination geometry with the Cu(II) ion situated on a crystallographic inversion center. The two Schiff base ligands are coordinated in a trans fashion. In the crystal structure, non-classical inter­molecular C—H⋯O hydrogen bonds involving the ether O atoms link the Schiff base mol­ecules into a two-dimensional network parallel to (101). International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959917/ /pubmed/21581118 http://dx.doi.org/10.1107/S1600536808035289 Text en © Datta et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Datta, Amitabha
Huang, Jui-Hsien
Lee, Hon Man
Bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title Bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_full Bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_fullStr Bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_full_unstemmed Bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_short Bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) N,O (1)}copper(II)
title_sort bis{2-meth­oxy-6-[(3-methoxy­prop­yl)imino­meth­yl]phenolato-κ(2) n,o (1)}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959917/
https://www.ncbi.nlm.nih.gov/pubmed/21581118
http://dx.doi.org/10.1107/S1600536808035289
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