Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate

The mol­ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu—μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core. Intramolecular O—H⋯S hydrogen bonds may stabilize...

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Detalles Bibliográficos
Autores principales: Zhang, Qing, Liu, Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959921/
https://www.ncbi.nlm.nih.gov/pubmed/21581154
http://dx.doi.org/10.1107/S1600536808035241
Descripción
Sumario:The mol­ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu—μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core. Intramolecular O—H⋯S hydrogen bonds may stabilize the structure. Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12).

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