Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate

The mol­ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu—μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core. Intramolecular O—H⋯S hydrogen bonds may stabilize...

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Detalles Bibliográficos
Autores principales: Zhang, Qing, Liu, Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959921/
https://www.ncbi.nlm.nih.gov/pubmed/21581154
http://dx.doi.org/10.1107/S1600536808035241
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author Zhang, Qing
Liu, Min
author_facet Zhang, Qing
Liu, Min
author_sort Zhang, Qing
collection PubMed
description The mol­ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu—μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core. Intramolecular O—H⋯S hydrogen bonds may stabilize the structure. Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12).
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spelling pubmed-29599212010-12-30 Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate Zhang, Qing Liu, Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [Cu(2)Mo(2)Br(2)(C(7)H(14)NS(2))(2)S(4)]·2C(3)H(7)OH, comprises one [(i-C(3)H(7))(2)NCS(2)](2)Mo(2)S(4) unit and two CuBr units held together by six Cu—μ(3)-S bonds, thus forming a cubane-like Mo(2)S(4)Cu(2) core. Intramolecular O—H⋯S hydrogen bonds may stabilize the structure. Two methyl groups of the two independent solvent molecules are disordered over two positions and were refined with occupancies of 0.733 (12) and 0.267 (12). International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959921/ /pubmed/21581154 http://dx.doi.org/10.1107/S1600536808035241 Text en © Zhang and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Qing
Liu, Min
Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate
title Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate
title_full Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate
title_fullStr Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate
title_full_unstemmed Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate
title_short Dibromidobis(N,N-diethyl­dithio­carbamato-κ(2) S,S′)tetra-μ(3)-sulfido-dicopper(I)dimolybdenum(V) isopropanol disolvate
title_sort dibromidobis(n,n-diethyl­dithio­carbamato-κ(2) s,s′)tetra-μ(3)-sulfido-dicopper(i)dimolybdenum(v) isopropanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959921/
https://www.ncbi.nlm.nih.gov/pubmed/21581154
http://dx.doi.org/10.1107/S1600536808035241
work_keys_str_mv AT zhangqing dibromidobisnndiethyldithiocarbamatok2sstetram3sulfidodicopperidimolybdenumvisopropanoldisolvate
AT liumin dibromidobisnndiethyldithiocarbamatok2sstetram3sulfidodicopperidimolybdenumvisopropanoldisolvate

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