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Ethyl 2-[(E)-4-(dimethyl­amino)benzyl­idenehydrazino]-5-nitro­benzoate

The title compound, C(18)H(20)N(4)O(4), exists in the E configuration with respect to the C=N bond of the methyl­idine unit. The dihedral angle between the two benzene rings is 9.01 (6)°. An intra­molecular N—H⋯O hydrogen bond involving the benzoate unit generates an S(6) ring motif. In the crystal,...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Adhikari, Adithya, Patil, P. S., Kalluraya, B., Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959927/
https://www.ncbi.nlm.nih.gov/pubmed/21581265
http://dx.doi.org/10.1107/S1600536808035939
Descripción
Sumario:The title compound, C(18)H(20)N(4)O(4), exists in the E configuration with respect to the C=N bond of the methyl­idine unit. The dihedral angle between the two benzene rings is 9.01 (6)°. An intra­molecular N—H⋯O hydrogen bond involving the benzoate unit generates an S(6) ring motif. In the crystal, the mol­ecules are linked by weak C—H⋯O inter­actions into infinite chains along the b axis. These chains are further connected into sheets parallel to the ab plane which are stacked approximately along the c axis. A C—H⋯π inter­action is also observed.