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Ethyl 2-[(E)-4-(dimethylamino)benzylidenehydrazino]-5-nitrobenzoate
The title compound, C(18)H(20)N(4)O(4), exists in the E configuration with respect to the C=N bond of the methylidine unit. The dihedral angle between the two benzene rings is 9.01 (6)°. An intramolecular N—H⋯O hydrogen bond involving the benzoate unit generates an S(6) ring motif. In the crystal,...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959927/ https://www.ncbi.nlm.nih.gov/pubmed/21581265 http://dx.doi.org/10.1107/S1600536808035939 |
Sumario: | The title compound, C(18)H(20)N(4)O(4), exists in the E configuration with respect to the C=N bond of the methylidine unit. The dihedral angle between the two benzene rings is 9.01 (6)°. An intramolecular N—H⋯O hydrogen bond involving the benzoate unit generates an S(6) ring motif. In the crystal, the molecules are linked by weak C—H⋯O interactions into infinite chains along the b axis. These chains are further connected into sheets parallel to the ab plane which are stacked approximately along the c axis. A C—H⋯π interaction is also observed. |
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