1,5-Bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione

In the title mol­ecule, C(21)H(16)Cl(2)O(2)S, the five-membered ring is rotationally disordered between two orientations in a 1:1 ratio. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules related by translation along the a axis into chains, which are further combined...

Descripción completa

Detalles Bibliográficos
Autores principales: Huang, Xianqiang, Xin, Feng, Shi, Qiu-Lan, Wang, Yong, Wei, Guo-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959928/
https://www.ncbi.nlm.nih.gov/pubmed/21581422
http://dx.doi.org/10.1107/S1600536808038993
_version_ 1782188617171468288
author Huang, Xianqiang
Xin, Feng
Shi, Qiu-Lan
Wang, Yong
Wei, Guo-Dong
author_facet Huang, Xianqiang
Xin, Feng
Shi, Qiu-Lan
Wang, Yong
Wei, Guo-Dong
author_sort Huang, Xianqiang
collection PubMed
description In the title mol­ecule, C(21)H(16)Cl(2)O(2)S, the five-membered ring is rotationally disordered between two orientations in a 1:1 ratio. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules related by translation along the a axis into chains, which are further combined into layers parallel to the bc plane via C—H⋯π inter­actions. The crystal studied was a racemic twin with a 0.37 (19):0.63 (19) domain ratio.
format Text
id pubmed-2959928
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29599282010-12-30 1,5-Bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione Huang, Xianqiang Xin, Feng Shi, Qiu-Lan Wang, Yong Wei, Guo-Dong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(21)H(16)Cl(2)O(2)S, the five-membered ring is rotationally disordered between two orientations in a 1:1 ratio. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds link mol­ecules related by translation along the a axis into chains, which are further combined into layers parallel to the bc plane via C—H⋯π inter­actions. The crystal studied was a racemic twin with a 0.37 (19):0.63 (19) domain ratio. International Union of Crystallography 2008-11-26 /pmc/articles/PMC2959928/ /pubmed/21581422 http://dx.doi.org/10.1107/S1600536808038993 Text en © Huang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Huang, Xianqiang
Xin, Feng
Shi, Qiu-Lan
Wang, Yong
Wei, Guo-Dong
1,5-Bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione
title 1,5-Bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione
title_full 1,5-Bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione
title_fullStr 1,5-Bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione
title_full_unstemmed 1,5-Bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione
title_short 1,5-Bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione
title_sort 1,5-bis(4-chloro­phen­yl)-3-(2-thien­yl)pentane-1,5-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959928/
https://www.ncbi.nlm.nih.gov/pubmed/21581422
http://dx.doi.org/10.1107/S1600536808038993
work_keys_str_mv AT huangxianqiang 15bis4chlorophenyl32thienylpentane15dione
AT xinfeng 15bis4chlorophenyl32thienylpentane15dione
AT shiqiulan 15bis4chlorophenyl32thienylpentane15dione
AT wangyong 15bis4chlorophenyl32thienylpentane15dione
AT weiguodong 15bis4chlorophenyl32thienylpentane15dione

Ejemplares similares