Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate]

In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa­hedrally coordinated by two bridging 1,4-anhydro­erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti­tactical polymeric cha...

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Detalles Bibliográficos
Autores principales: Kerscher, Tobias, Zeller, Patrick, Mayer, Peter, Klüfers, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959930/
https://www.ncbi.nlm.nih.gov/pubmed/21581226
http://dx.doi.org/10.1107/S1600536808039640
Descripción
Sumario:In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa­hedrally coordinated by two bridging 1,4-anhydro­erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti­tactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydro­erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.

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