Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate]

In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa­hedrally coordinated by two bridging 1,4-anhydro­erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti­tactical polymeric cha...

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Detalles Bibliográficos
Autores principales: Kerscher, Tobias, Zeller, Patrick, Mayer, Peter, Klüfers, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959930/
https://www.ncbi.nlm.nih.gov/pubmed/21581226
http://dx.doi.org/10.1107/S1600536808039640
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author Kerscher, Tobias
Zeller, Patrick
Mayer, Peter
Klüfers, Peter
author_facet Kerscher, Tobias
Zeller, Patrick
Mayer, Peter
Klüfers, Peter
author_sort Kerscher, Tobias
collection PubMed
description In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa­hedrally coordinated by two bridging 1,4-anhydro­erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti­tactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydro­erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated.
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spelling pubmed-29599302010-12-30 Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate] Kerscher, Tobias Zeller, Patrick Mayer, Peter Klüfers, Peter Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Na(C(4)H(7)O(3))(H(2)O)(2)]·H(2)O}(n), the sodium ion is octa­hedrally coordinated by two bridging 1,4-anhydro­erythritolate ligands, unexpectedly coordinated by the ring oxygen and four water ligands. This bonding pattern leads to one-dimensional anti­tactical polymeric chains along [010]. One of the exocyclic O atoms of the anhydro­erythritolate group is an acceptor in four hydrogen bonds, giving further evidence that it is deprotonated. International Union of Crystallography 2008-11-29 /pmc/articles/PMC2959930/ /pubmed/21581226 http://dx.doi.org/10.1107/S1600536808039640 Text en © Kerscher et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kerscher, Tobias
Zeller, Patrick
Mayer, Peter
Klüfers, Peter
Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate]
title Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_full Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_fullStr Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_full_unstemmed Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_short Poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(I)] monohydrate]
title_sort poly[[μ-1,4-anhydro­erythritolato-di-μ-aqua-sodium(i)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959930/
https://www.ncbi.nlm.nih.gov/pubmed/21581226
http://dx.doi.org/10.1107/S1600536808039640
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